Characterization of electrochemically reduced dicadmium stannate View Full Text


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Article Info

DATE

1988-07

AUTHORS

T. Hashemi, C. A. Hogarth, F. Golestani-Fard

ABSTRACT

The two stable species of dicadmium stannate, namely oxidized (yellow) and reduced (green), have been studied using X-ray diffraction (XRD), Auger, and electron spectroscopy for chemical analysis (ESCA) techniques. Semiquantitative ESCA showed a chemical formula of Cd2SnO4 for yellow and Cd2SnO2 for the green compound. It appeared that both tin and cadmium can undergo a change in valency state during the electrochemical reduction. This explains the high energy density of the compound when used as active material for the negative electrode in rechargeable batteries. The variation of electrical conductivity of dicadmium stannate prepared under different conditions can be explained in terms of the reduction of tin, cadmium or both in the original compound. More... »

PAGES

2645-2648

References to SciGraph publications

  • 1979-10. The electrical properties of monocadmium and dicadmium stannates in JOURNAL OF MATERIALS SCIENCE
  • 1983-12. Formation of cadmium stannates studied by electron spectroscopy in JOURNAL OF MATERIALS SCIENCE
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1007/bf01111927

    DOI

    http://dx.doi.org/10.1007/bf01111927

    DIMENSIONS

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