Decomposition of solid explosives by laser irradiation: A mass spectrometric study View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1987-03

AUTHORS

Tong B. Tang, M. M. Chaudhri, Caroline S. Rees, S. J. Mullock

ABSTRACT

Experimental investigations have been made in which single crystals of solid explosives such as cyclotrimethylene trinitramine, RDX, pentaerythritol tetranitrate, PETN, AgN3 and Pb(N3)2, were irradiated with a focused laser beam of wavelength 266 nm and duration ≈ 5 nsec in an ultra high vacuum system housing a fast and sensitive time-of-flight mass spectrometer. From the mass spectra (both +ve and -ve ions) of the chemical species obtained, possible decomposition schemes of RDX and PETN have been proposed. For silver and lead azides, the laser irradiation did not cause explosions if the power density was sufficiently low, but micrometre size craters were formed. In the mass spectra of AgN3 products N3− and silver cluster ions, Agn+, have been found for the first time. It has been suggested that such investigations may possibly throw some light on our understanding of the reactions taking place in a deflagration/detonation wave. More... »

PAGES

1037-1044

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01103548

DOI

http://dx.doi.org/10.1007/bf01103548

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034129769


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