Thermal decomposition of trialkylaminalanes View Full Text


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Article Info

DATE

1975-08

AUTHORS

G. N. Nechiporenko, L. B. Petukhova, A. S. Rozenberg

ABSTRACT

ConclusionsThe decomposition of AlH3·NMe3 and AlH3·NEt3 under isothermal conditions above the melting point proceeds simultaneously both in the gas and in the condensed phase. Decomposition in the gas phase leads to the formation of hydrogen, metallic aluminum, and the corresponding amine. Decomposition in the condensed phase leads to the formation of an amine and a solvated polymer form of aluminum hydride,A scheme was proposed for the decomposition of trialkylaminalanes, and a kinetic analysis of it was cited, as a result of which kinetic equations were obtained, reflecting the experimentally observed principles in the nature of the gas evolution. The rate constants of the decomposition of AlH3 · NMe3 and AlH3 · NEt3 in the gas phase, as well as the effective rate constant of the decomposition of AlH3, were determined. More... »

PAGES

1584-1591

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01099999

DOI

http://dx.doi.org/10.1007/bf01099999

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026524217


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