Formation and growth of iron nitrides during ion-nitriding View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1987-08

AUTHORS

E. Metin, O. T. Inal

ABSTRACT

In order to clarify the formation and growth kinetics of iron nitrides, Fe2N (ζ), Fe2–3N (ɛ) and Fe4N (γ′), on the surface of iron during ion-nitriding, and their contribution to the mechanism of ion-nitriding coarse-grained specimens (2 to 6 mm) were ion-nitrided in pure nitrogen and nitrogen-hydrogen (20%–80%) plasma at temperatures between 500 and 600°C. Reflection electron diffraction (RED) showed immediate formation of the nitrides. Growth of these phases in latter stages of ion-nitriding was studied using optical microscopy and X-ray diffraction. The mechanism of the nitride layer formation is discussed and compared with the existing gas nitriding data. In the case region, Fe4N (γ′) and Fe16N2 (α″) precipitation was observed to occur under all experimental conditions studied. Case depth is seen to be parabolic with time and nitriding rate increases slightly when nitrogen-hydrogen plasma is used. Discussions are given to explain the difference in the nitriding efficiency under two different plasma compositions. More... »

PAGES

2783-2788

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01086471

DOI

http://dx.doi.org/10.1007/bf01086471

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004270237


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