Complexation of carboxylic acids and anions by alpha and beta cyclodextrins View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1989-08

AUTHORS

Robert I. Gelb, Lowell M. Schwartz

ABSTRACT

A pH potentiometric method is used to measure complex formation constants of aqueous alpha- and/or beta-cyclodextrin with several carboxylic acids and carboxylate anions: butyric acid/butyrate; valeric acid/valerate; hexanoic acid/hexanoate; octanoic acid/octanoate; decanoic acid/decanoate; cyclohexanecarboxylic acid/cyclohexanecarboxylate and benzoic acid/benzoate. Standard enthalpies and entropies of complex formation are calculated from the temperature dependencies of the equilibrium constants. These thermodynamic parameters of the alpha-cyclodextrin complexes largely conform to a correlation based on complexes with other substrate species previously reported. Both standard enthalpies and entropies of formation of beta-cyclodextrin complexes are found to be more positive than the corresponding complexes of alpha-cyclodextrin with the same substrates. These observations lead to insights into the bonding mechanism of cyclodextrin complexation. More... »

PAGES

465-476

References to SciGraph publications

  • 1978. Cyclodextrin Chemistry in NONE
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf01079783

    DOI

    http://dx.doi.org/10.1007/bf01079783

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1035548231


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0601", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Biochemistry and Cell Biology", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/06", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Biological Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "University of Massachusetts Amherst", 
              "id": "https://www.grid.ac/institutes/grid.266683.f", 
              "name": [
                "Department of Chemistry, University of Massachusetts, 02125, Boston, MA, USA"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Gelb", 
            "givenName": "Robert I.", 
            "id": "sg:person.012714514021.83", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012714514021.83"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "University of Massachusetts Amherst", 
              "id": "https://www.grid.ac/institutes/grid.266683.f", 
              "name": [
                "Department of Chemistry, University of Massachusetts, 02125, Boston, MA, USA"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Schwartz", 
            "givenName": "Lowell M.", 
            "id": "sg:person.011604674345.32", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011604674345.32"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.1016/s0003-2670(01)83225-6", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1005161467"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1248/cpb.24.1155", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1016946057"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/jps.2600650316", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1026128046"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1246/bcsj.51.2737", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1047222990"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://app.dimensions.ai/details/publication/pub.1050942581", 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/978-3-642-66842-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1050942581", 
              "https://doi.org/10.1007/978-3-642-66842-5"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/978-3-642-66842-5", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1050942581", 
              "https://doi.org/10.1007/978-3-642-66842-5"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00298a003", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055721345"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00387a022", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055728355"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00397a027", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055729206"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00423a018", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055731288"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00448a009", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055733312"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00477a051", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055735706"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00501a038", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055737590"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ja00504a001", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055737760"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "1989-08", 
        "datePublishedReg": "1989-08-01", 
        "description": "A pH potentiometric method is used to measure complex formation constants of aqueous alpha- and/or beta-cyclodextrin with several carboxylic acids and carboxylate anions: butyric acid/butyrate; valeric acid/valerate; hexanoic acid/hexanoate; octanoic acid/octanoate; decanoic acid/decanoate; cyclohexanecarboxylic acid/cyclohexanecarboxylate and benzoic acid/benzoate. Standard enthalpies and entropies of complex formation are calculated from the temperature dependencies of the equilibrium constants. These thermodynamic parameters of the alpha-cyclodextrin complexes largely conform to a correlation based on complexes with other substrate species previously reported. Both standard enthalpies and entropies of formation of beta-cyclodextrin complexes are found to be more positive than the corresponding complexes of alpha-cyclodextrin with the same substrates. These observations lead to insights into the bonding mechanism of cyclodextrin complexation.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/bf01079783", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1119385", 
            "issn": [
              "1388-3127", 
              "2212-1765"
            ], 
            "name": "Journal of Inclusion Phenomena and Macrocyclic Chemistry", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "4", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "7"
          }
        ], 
        "name": "Complexation of carboxylic acids and anions by alpha and beta cyclodextrins", 
        "pagination": "465-476", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "a955f8b58c078b1bd1df05bc09b99af0c185ff69de2563e7b0f259ed32be6969"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf01079783"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1035548231"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf01079783", 
          "https://app.dimensions.ai/details/publication/pub.1035548231"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-11T13:30", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000370_0000000370/records_46751_00000001.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007/BF01079783"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01079783'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01079783'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01079783'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01079783'


     

    This table displays all metadata directly associated to this object as RDF triples.

    110 TRIPLES      21 PREDICATES      41 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf01079783 schema:about anzsrc-for:06
    2 anzsrc-for:0601
    3 schema:author N87aa09d18ef249dd9b1078342fd91e28
    4 schema:citation sg:pub.10.1007/978-3-642-66842-5
    5 https://app.dimensions.ai/details/publication/pub.1050942581
    6 https://doi.org/10.1002/jps.2600650316
    7 https://doi.org/10.1016/s0003-2670(01)83225-6
    8 https://doi.org/10.1021/ja00298a003
    9 https://doi.org/10.1021/ja00387a022
    10 https://doi.org/10.1021/ja00397a027
    11 https://doi.org/10.1021/ja00423a018
    12 https://doi.org/10.1021/ja00448a009
    13 https://doi.org/10.1021/ja00477a051
    14 https://doi.org/10.1021/ja00501a038
    15 https://doi.org/10.1021/ja00504a001
    16 https://doi.org/10.1246/bcsj.51.2737
    17 https://doi.org/10.1248/cpb.24.1155
    18 schema:datePublished 1989-08
    19 schema:datePublishedReg 1989-08-01
    20 schema:description A pH potentiometric method is used to measure complex formation constants of aqueous alpha- and/or beta-cyclodextrin with several carboxylic acids and carboxylate anions: butyric acid/butyrate; valeric acid/valerate; hexanoic acid/hexanoate; octanoic acid/octanoate; decanoic acid/decanoate; cyclohexanecarboxylic acid/cyclohexanecarboxylate and benzoic acid/benzoate. Standard enthalpies and entropies of complex formation are calculated from the temperature dependencies of the equilibrium constants. These thermodynamic parameters of the alpha-cyclodextrin complexes largely conform to a correlation based on complexes with other substrate species previously reported. Both standard enthalpies and entropies of formation of beta-cyclodextrin complexes are found to be more positive than the corresponding complexes of alpha-cyclodextrin with the same substrates. These observations lead to insights into the bonding mechanism of cyclodextrin complexation.
    21 schema:genre research_article
    22 schema:inLanguage en
    23 schema:isAccessibleForFree false
    24 schema:isPartOf N48d31108d67d478e86e10dcb2c38d668
    25 N5cc28f5534204b2e984ae0253ac27ca8
    26 sg:journal.1119385
    27 schema:name Complexation of carboxylic acids and anions by alpha and beta cyclodextrins
    28 schema:pagination 465-476
    29 schema:productId N77b5fa1b3694497db7bf5f1206133ebd
    30 Na19c84f1b24448c591aa914e340fb449
    31 Ne1dc7152702245a39e146bfa255997b6
    32 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035548231
    33 https://doi.org/10.1007/bf01079783
    34 schema:sdDatePublished 2019-04-11T13:30
    35 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    36 schema:sdPublisher Nb5c86b59e06141ea9ee45c72b5ace3bc
    37 schema:url http://link.springer.com/10.1007/BF01079783
    38 sgo:license sg:explorer/license/
    39 sgo:sdDataset articles
    40 rdf:type schema:ScholarlyArticle
    41 N0cf3d020821741c1a1a046fd905eb9e8 rdf:first sg:person.011604674345.32
    42 rdf:rest rdf:nil
    43 N48d31108d67d478e86e10dcb2c38d668 schema:volumeNumber 7
    44 rdf:type schema:PublicationVolume
    45 N5cc28f5534204b2e984ae0253ac27ca8 schema:issueNumber 4
    46 rdf:type schema:PublicationIssue
    47 N77b5fa1b3694497db7bf5f1206133ebd schema:name doi
    48 schema:value 10.1007/bf01079783
    49 rdf:type schema:PropertyValue
    50 N87aa09d18ef249dd9b1078342fd91e28 rdf:first sg:person.012714514021.83
    51 rdf:rest N0cf3d020821741c1a1a046fd905eb9e8
    52 Na19c84f1b24448c591aa914e340fb449 schema:name readcube_id
    53 schema:value a955f8b58c078b1bd1df05bc09b99af0c185ff69de2563e7b0f259ed32be6969
    54 rdf:type schema:PropertyValue
    55 Nb5c86b59e06141ea9ee45c72b5ace3bc schema:name Springer Nature - SN SciGraph project
    56 rdf:type schema:Organization
    57 Ne1dc7152702245a39e146bfa255997b6 schema:name dimensions_id
    58 schema:value pub.1035548231
    59 rdf:type schema:PropertyValue
    60 anzsrc-for:06 schema:inDefinedTermSet anzsrc-for:
    61 schema:name Biological Sciences
    62 rdf:type schema:DefinedTerm
    63 anzsrc-for:0601 schema:inDefinedTermSet anzsrc-for:
    64 schema:name Biochemistry and Cell Biology
    65 rdf:type schema:DefinedTerm
    66 sg:journal.1119385 schema:issn 1388-3127
    67 2212-1765
    68 schema:name Journal of Inclusion Phenomena and Macrocyclic Chemistry
    69 rdf:type schema:Periodical
    70 sg:person.011604674345.32 schema:affiliation https://www.grid.ac/institutes/grid.266683.f
    71 schema:familyName Schwartz
    72 schema:givenName Lowell M.
    73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011604674345.32
    74 rdf:type schema:Person
    75 sg:person.012714514021.83 schema:affiliation https://www.grid.ac/institutes/grid.266683.f
    76 schema:familyName Gelb
    77 schema:givenName Robert I.
    78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012714514021.83
    79 rdf:type schema:Person
    80 sg:pub.10.1007/978-3-642-66842-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050942581
    81 https://doi.org/10.1007/978-3-642-66842-5
    82 rdf:type schema:CreativeWork
    83 https://app.dimensions.ai/details/publication/pub.1050942581 schema:CreativeWork
    84 https://doi.org/10.1002/jps.2600650316 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026128046
    85 rdf:type schema:CreativeWork
    86 https://doi.org/10.1016/s0003-2670(01)83225-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005161467
    87 rdf:type schema:CreativeWork
    88 https://doi.org/10.1021/ja00298a003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055721345
    89 rdf:type schema:CreativeWork
    90 https://doi.org/10.1021/ja00387a022 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055728355
    91 rdf:type schema:CreativeWork
    92 https://doi.org/10.1021/ja00397a027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055729206
    93 rdf:type schema:CreativeWork
    94 https://doi.org/10.1021/ja00423a018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055731288
    95 rdf:type schema:CreativeWork
    96 https://doi.org/10.1021/ja00448a009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055733312
    97 rdf:type schema:CreativeWork
    98 https://doi.org/10.1021/ja00477a051 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055735706
    99 rdf:type schema:CreativeWork
    100 https://doi.org/10.1021/ja00501a038 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055737590
    101 rdf:type schema:CreativeWork
    102 https://doi.org/10.1021/ja00504a001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055737760
    103 rdf:type schema:CreativeWork
    104 https://doi.org/10.1246/bcsj.51.2737 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047222990
    105 rdf:type schema:CreativeWork
    106 https://doi.org/10.1248/cpb.24.1155 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016946057
    107 rdf:type schema:CreativeWork
    108 https://www.grid.ac/institutes/grid.266683.f schema:alternateName University of Massachusetts Amherst
    109 schema:name Department of Chemistry, University of Massachusetts, 02125, Boston, MA, USA
    110 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...