Clathrates of allene dimers. X-ray crystal structures of two inclusion compounds withp-xylene and phenyloxirane View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1991-03

AUTHORS

Edwin Weber, Wilhelm Seichter, Israel Goldberg, Georg Will, Hans-Jürgen Dasting

ABSTRACT

Allene dimers of the 1,2-dimethylenecyclobutane-type with bridged aromatic groups (fluorenylidene units) and extra substituents (Me,t-Bu)2a-c have been synthesized and characterized by elemental analysis and spectroscopic data. Their crystal inclusion properties are reported. The unsubstituted compound2a yields only an inclusion compound withp-xylene, while methyl-substituted2b enclathrates a broad range of molecules. On the other hand, thet-butyl-substituted2c does not form clathrates, crystallizing as a pure compound. Complete structural descriptions of the two inclusion compounds2a-p-xylene (2:1) and2b-phenyloxirane (1:1) are given. They represent interstitial clathrates. Crystallographic data of the 1:1p-xylene clathrate of2b (which is isomorphous to its phenyloxirane analog) and of unsolvated2c are also reported. As indicated by the results, substitutional effects critically influence the inclusion properties of the new clathrate family. More... »

PAGES

267-282

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01066210

DOI

http://dx.doi.org/10.1007/bf01066210

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041637834


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