Inclusion compounds: The products of the interaction of silicon, germanium and boron fluorides with crown ethers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-03

AUTHORS

Yurii A. Simonov, Marina S. Fonari, Janusz Lipkowski, Vladimir O. Gelmboldt, Edward V. Ganin

ABSTRACT

This review deals with the problem of the interaction of Si(IV), Ge(IV) and B(III) fluorides with crown ethers and their aza analogues. The crystallographic structures have been determined of the stable products obtained by the interaction of H2SiF6 solution with the following crown ethers: 18-crown-6 (18C6), monoaza-18C6 (MA18C6), 1,10-diaza-18C6 (DA18C6) and 1,7-diaza-15C5 (DA 15C5). The complexes obtained are stabilized by a system of H-bonds of the O-H... O, N-H. ... O, N-H...F and O-H ... F types. For H2GeF6 the adducts obtained are similar to those obtained using H2SiF6. The crystal structures of three new boron fluoride-containing complexes with 18-membered crown ethers are also described. During macrocycle complexation the guest entities undergo chemical transformations which are stabilized by creation of the H- bond system. The results of vibrational and NMR spectra are also discussed. More... »

PAGES

149-161

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01053428

DOI

http://dx.doi.org/10.1007/bf01053428

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040052374


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