Complexes of tri- and tetra-protonated forms of 1,4,8,12-tetraazacyclopentadecane with chloride, nitrate, iodate, and sulfate ions in aqueous media: I. Formation ... View Full Text


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Article Info

DATE

1991-12

AUTHORS

Joseph S. Alper, Robert I. Gelb, Marietta H. Schwartz

ABSTRACT

Complexation stoichiometries and formation constants of tri- and tetra-protonated forms of 1,4,8,12-tetraazacyclopentadecane with NO3−, Cl−, IO3− and SO42− ions are determined by pH potentiometric and13C NMR spectrometric measurements. Estimates of ΔH and ΔS are obtained from the values of the temperature dependent formation constants and acid dissociation constants. All four anions form only 1 : 1 complexes with the triprotonated amine species. NO3− and Cl− form 1 : 1 complexes only with the tetraprotonated amine, while IO3− and SO42− form both 1 : 1 and 2 : 1 complexes. The complexation behavior is interpreted in terms of solvation and internal hydrogen bonding interactions. More... »

PAGES

333-348

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01041412

DOI

http://dx.doi.org/10.1007/bf01041412

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028095487


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