Stabilization of germanium(IV) aquafluorocompounds in host-guest type complexes with crown ethers. synthesis, crystal structure and ir spectra of the complexes ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-12

AUTHORS

Vladimir O. Gelmboldt, Edward V. Ganin, Larisa V. Ostapchuk, Janusz Lipkowski, Alexander A. Dvorkin, Yurii A. Simonov, Marina S. Fonari

ABSTRACT

Stable products have been obtained from the interaction of GeO2-HF solution with 18-membered crown ethers, 1,10-diaza-l8-crown-6 and 18-crown 6. Complexes were characterized by X-ray analysis and IR spectroscopy. Both Ge(IV) aquafluorocompounds are isostructural with their Si analogues. It was established that in the host-guest type complexes the germanium moiety as a central atom has been stabilized in the form of octahedral complexes. The host-guest interaction occurs by means of O-H(W)...Ocr, OH...F and N-H...F hydrogen bonds. More... »

PAGES

287-299

References to SciGraph publications

  • 1991-01. Stabilization of H2O ⁗ BF3 by hydrogen bonding to 18-crown-6 in JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1007/bf01041114

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    http://dx.doi.org/10.1007/bf01041114

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    149 rdf:type schema:Organization
     




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