Ontology type: schema:ScholarlyArticle
1992-08
AUTHORSE. Theodoridou, A. D. Jannakoudakis, P. D. Jannakoudakis, S. Antoniadou, J. O. Besenhard
ABSTRACTThe behaviour of a new kind of metalloporphyrin catalyst electrode for reduction of oxygen, characterized by a metal and ligand charged (MLC) water soluble metalloporphyrin system and a surface oxidized carbon fibre substrate exhibiting cation exchanger properties, is investigated by cyclic voltammetry and by impedance spectroscopy. Results with Fe- and Co-MLC-metalloporphyrins clearly indicate that they are electrocatalytically active so long as the transition metals exist in their +3 oxidation state. Compared to conventional metalloporphyrin electrodes, which are obtained after adsorption procedures, this new kind of electrode has several advantages, i.e. it bears larger quantity of catalytically active monomeric metalloporphyrin molecules it is more resistant to rinsing and can be reactivated by addition of the metalloporphyrin to the aqueous electrolyte solution. These advantages allow the application of this electrode in fuel cells. More... »
PAGES733-737
http://scigraph.springernature.com/pub.10.1007/bf01027502
DOIhttp://dx.doi.org/10.1007/bf01027502
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1000283201
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Aristotle University of Thessaloniki",
"id": "https://www.grid.ac/institutes/grid.4793.9",
"name": [
"Institute of Physical Chemistry, Aristotelian University, Thessaloniki, Greece"
],
"type": "Organization"
},
"familyName": "Theodoridou",
"givenName": "E.",
"id": "sg:person.016532067032.32",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016532067032.32"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Aristotle University of Thessaloniki",
"id": "https://www.grid.ac/institutes/grid.4793.9",
"name": [
"Institute of Physical Chemistry, Aristotelian University, Thessaloniki, Greece"
],
"type": "Organization"
},
"familyName": "Jannakoudakis",
"givenName": "A. D.",
"id": "sg:person.013436334465.08",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013436334465.08"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Aristotle University of Thessaloniki",
"id": "https://www.grid.ac/institutes/grid.4793.9",
"name": [
"Institute of Physical Chemistry, Aristotelian University, Thessaloniki, Greece"
],
"type": "Organization"
},
"familyName": "Jannakoudakis",
"givenName": "P. D.",
"id": "sg:person.016661553525.03",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016661553525.03"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Aristotle University of Thessaloniki",
"id": "https://www.grid.ac/institutes/grid.4793.9",
"name": [
"Institute of Physical Chemistry, Aristotelian University, Thessaloniki, Greece"
],
"type": "Organization"
},
"familyName": "Antoniadou",
"givenName": "S.",
"id": "sg:person.010614754655.42",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010614754655.42"
],
"type": "Person"
},
{
"affiliation": {
"name": [
"Institute of Inorganic Chemistry, Westf\u00e4llische Wilhelms University, M\u00fcnster, Germany"
],
"type": "Organization"
},
"familyName": "Besenhard",
"givenName": "J. O.",
"id": "sg:person.01144123216.14",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01144123216.14"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1042/bj0780793",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002465789"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1042/bj0780793",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1002465789"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0022-0728(80)80078-7",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1011049302"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0379-6779(89)90651-6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1017828265"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0379-6779(89)90651-6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1017828265"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0008-6223(77)90047-1",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018044890"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0008-6223(77)90047-1",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1018044890"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0379-6779(86)90134-7",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1022553188"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0379-6779(86)90134-7",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1022553188"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0379-6779(89)90773-x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029828476"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0379-6779(89)90773-x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1029828476"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0379-6779(89)90652-8",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1042778781"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/0379-6779(89)90652-8",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1042778781"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/bf01008872",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1047889391",
"https://doi.org/10.1007/bf01008872"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1016/s0022-0728(78)80278-2",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1050409011"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/j100211a043",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1055659457"
],
"type": "CreativeWork"
}
],
"datePublished": "1992-08",
"datePublishedReg": "1992-08-01",
"description": "The behaviour of a new kind of metalloporphyrin catalyst electrode for reduction of oxygen, characterized by a metal and ligand charged (MLC) water soluble metalloporphyrin system and a surface oxidized carbon fibre substrate exhibiting cation exchanger properties, is investigated by cyclic voltammetry and by impedance spectroscopy. Results with Fe- and Co-MLC-metalloporphyrins clearly indicate that they are electrocatalytically active so long as the transition metals exist in their +3 oxidation state. Compared to conventional metalloporphyrin electrodes, which are obtained after adsorption procedures, this new kind of electrode has several advantages, i.e. it bears larger quantity of catalytically active monomeric metalloporphyrin molecules it is more resistant to rinsing and can be reactivated by addition of the metalloporphyrin to the aqueous electrolyte solution. These advantages allow the application of this electrode in fuel cells.",
"genre": "research_article",
"id": "sg:pub.10.1007/bf01027502",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1049623",
"issn": [
"0021-891X",
"1572-8838"
],
"name": "Journal of Applied Electrochemistry",
"type": "Periodical"
},
{
"issueNumber": "8",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "22"
}
],
"name": "Carbon fibre based conductive ion exchangers as support for metal and ligand charged metalloporphyrin electrocatalysts",
"pagination": "733-737",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"0158a20b24e815c7e303e32b4d0ee5bd1aeb640b11af72dda1ba1a2ae668df46"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf01027502"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1000283201"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf01027502",
"https://app.dimensions.ai/details/publication/pub.1000283201"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-11T00:59",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8697_00000479.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1007/BF01027502"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf01027502'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf01027502'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf01027502'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf01027502'
This table displays all metadata directly associated to this object as RDF triples.
122 TRIPLES
21 PREDICATES
37 URIs
19 LITERALS
7 BLANK NODES