Temperature dependence of the quadrupole interaction in potassium heptafluohafnate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1982-05

AUTHORS

W. V. Prestwich, I. A. Cunningham, T. J. Kennett

ABSTRACT

The quadrupole interaction between the tantalum nucleus and its environment in potassium heptafluohafnate incorporating radioactive181Hf has been studied over the temperature range from 77 K to 318 K. A discontinuity in the field gradient tensor is observed at 250 K together with a more gradual alteration with midpoint temperature of approximately 210 K. Below 250 K, the data indicate two inequivalent sites for the tantalum nuclei. The values obtained for the electric field gradient tensor suggest that motional averaging may be significant in this compound. More... »

PAGES

329-343

References to SciGraph publications

Journal

TITLE

Hyperfine Interactions

ISSUE

1

VOLUME

12

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf01026381

DOI

http://dx.doi.org/10.1007/bf01026381

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046008830


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