The determination of the second dissociation constant of sulfuric acid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1994-01

AUTHORS

P. Luts, J. Vanhees, J. Yperman, J. Mullens, L. C. Van Poucke

ABSTRACT

The second dissociation constant of sulfuric acid is determined in 1M NaClO4 at 25°C using an electrochemical cell without liquid junction consisting of a glass and a perchlorate electrode. By taking into account the association between the Na+ and SO42− ions an average value of 0.0184±0.0005 is found using three different methods. This corresponds with an apparent acidity constant KA2* of 0.095±0.003 More... »

PAGES

75-80

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00972609

DOI

http://dx.doi.org/10.1007/bf00972609

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004851145


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "Tessenderlo Chemie, B-3980, Tessenderlo, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Luts", 
        "givenName": "P.", 
        "id": "sg:person.01176444520.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01176444520.19"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Industri\u00eble Hogeschool Gemeenschapsonderwijs Limburg, B-3500, Hasselt, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vanhees", 
        "givenName": "J.", 
        "id": "sg:person.01244557720.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01244557720.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Hasselt", 
          "id": "https://www.grid.ac/institutes/grid.12155.32", 
          "name": [
            "Laboratory of Inorganic and Physical Chemistry, Limburgs Universitair Centrum, B-3590, Diepenbeek, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Yperman", 
        "givenName": "J.", 
        "id": "sg:person.01113450541.67", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01113450541.67"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Hasselt", 
          "id": "https://www.grid.ac/institutes/grid.12155.32", 
          "name": [
            "Laboratory of Inorganic and Physical Chemistry, Limburgs Universitair Centrum, B-3590, Diepenbeek, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mullens", 
        "givenName": "J.", 
        "id": "sg:person.0621537414.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0621537414.02"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Hasselt", 
          "id": "https://www.grid.ac/institutes/grid.12155.32", 
          "name": [
            "Laboratory of Inorganic and Physical Chemistry, Limburgs Universitair Centrum, B-3590, Diepenbeek, Belgium"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Van Poucke", 
        "givenName": "L. C.", 
        "id": "sg:person.016377441051.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016377441051.16"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf00647860", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001176177", 
          "https://doi.org/10.1007/bf00647860"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00647860", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001176177", 
          "https://doi.org/10.1007/bf00647860"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(64)80257-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030473557"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-1902(64)80257-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030473557"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.44.1515", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037514122"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr60137a007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1054082752"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100820a012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055680374"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01319a029", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055791815"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01418a009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055798101"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01626a015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055813885"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1994-01", 
    "datePublishedReg": "1994-01-01", 
    "description": "The second dissociation constant of sulfuric acid is determined in 1M NaClO4 at 25\u00b0C using an electrochemical cell without liquid junction consisting of a glass and a perchlorate electrode. By taking into account the association between the Na+ and SO42\u2212 ions an average value of 0.0184\u00b10.0005 is found using three different methods. This corresponds with an apparent acidity constant KA2* of 0.095\u00b10.003", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00972609", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1015946", 
        "issn": [
          "0095-9782", 
          "1572-8927"
        ], 
        "name": "Journal of Solution Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "23"
      }
    ], 
    "name": "The determination of the second dissociation constant of sulfuric acid", 
    "pagination": "75-80", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "171e25f7e92d7315b028437390b1f83a148a829ea71890889234396a00260ac7"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00972609"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1004851145"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00972609", 
      "https://app.dimensions.ai/details/publication/pub.1004851145"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T19:53", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8681_00000494.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF00972609"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00972609'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00972609'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00972609'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00972609'


 

This table displays all metadata directly associated to this object as RDF triples.

118 TRIPLES      21 PREDICATES      35 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00972609 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N53abb20560954836bf9a60077f0aa89c
4 schema:citation sg:pub.10.1007/bf00647860
5 https://doi.org/10.1016/0022-1902(64)80257-8
6 https://doi.org/10.1021/cr60137a007
7 https://doi.org/10.1021/j100820a012
8 https://doi.org/10.1021/ja01319a029
9 https://doi.org/10.1021/ja01418a009
10 https://doi.org/10.1021/ja01626a015
11 https://doi.org/10.1246/bcsj.44.1515
12 schema:datePublished 1994-01
13 schema:datePublishedReg 1994-01-01
14 schema:description The second dissociation constant of sulfuric acid is determined in 1M NaClO4 at 25°C using an electrochemical cell without liquid junction consisting of a glass and a perchlorate electrode. By taking into account the association between the Na+ and SO42− ions an average value of 0.0184±0.0005 is found using three different methods. This corresponds with an apparent acidity constant KA2* of 0.095±0.003
15 schema:genre research_article
16 schema:inLanguage en
17 schema:isAccessibleForFree false
18 schema:isPartOf N3e04fac1e7674e5c8174f12ea09600e6
19 N83594508e8094c0281740e677f314024
20 sg:journal.1015946
21 schema:name The determination of the second dissociation constant of sulfuric acid
22 schema:pagination 75-80
23 schema:productId N0e7f9009b95b40deaeff333260ac6dfc
24 N61039ce9bf5b4e00a88e475cc6819937
25 Ne5c4a246daf040c8826fa421bd9f36df
26 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004851145
27 https://doi.org/10.1007/bf00972609
28 schema:sdDatePublished 2019-04-10T19:53
29 schema:sdLicense https://scigraph.springernature.com/explorer/license/
30 schema:sdPublisher Nafc93056cade41219536876abc0aa46d
31 schema:url http://link.springer.com/10.1007/BF00972609
32 sgo:license sg:explorer/license/
33 sgo:sdDataset articles
34 rdf:type schema:ScholarlyArticle
35 N0a6202d0a65e4a81bdc22787f8b576d2 rdf:first sg:person.01113450541.67
36 rdf:rest N967405ef7720401ab327e5d8b8fd3bb6
37 N0e7f9009b95b40deaeff333260ac6dfc schema:name doi
38 schema:value 10.1007/bf00972609
39 rdf:type schema:PropertyValue
40 N3e04fac1e7674e5c8174f12ea09600e6 schema:issueNumber 1
41 rdf:type schema:PublicationIssue
42 N53abb20560954836bf9a60077f0aa89c rdf:first sg:person.01176444520.19
43 rdf:rest N9613217284b8479f9b6bc44f639b72d4
44 N61039ce9bf5b4e00a88e475cc6819937 schema:name dimensions_id
45 schema:value pub.1004851145
46 rdf:type schema:PropertyValue
47 N83594508e8094c0281740e677f314024 schema:volumeNumber 23
48 rdf:type schema:PublicationVolume
49 N9613217284b8479f9b6bc44f639b72d4 rdf:first sg:person.01244557720.16
50 rdf:rest N0a6202d0a65e4a81bdc22787f8b576d2
51 N967405ef7720401ab327e5d8b8fd3bb6 rdf:first sg:person.0621537414.02
52 rdf:rest Ndf061a31dc534f40a2b6a3920028b5bb
53 Nafc93056cade41219536876abc0aa46d schema:name Springer Nature - SN SciGraph project
54 rdf:type schema:Organization
55 Nd4937f2af9f34be08733cf075ebbebf3 schema:name Industriële Hogeschool Gemeenschapsonderwijs Limburg, B-3500, Hasselt, Belgium
56 rdf:type schema:Organization
57 Nddcf8e4cff504ca889a8462ac0cde651 schema:name Tessenderlo Chemie, B-3980, Tessenderlo, Belgium
58 rdf:type schema:Organization
59 Ndf061a31dc534f40a2b6a3920028b5bb rdf:first sg:person.016377441051.16
60 rdf:rest rdf:nil
61 Ne5c4a246daf040c8826fa421bd9f36df schema:name readcube_id
62 schema:value 171e25f7e92d7315b028437390b1f83a148a829ea71890889234396a00260ac7
63 rdf:type schema:PropertyValue
64 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
65 schema:name Chemical Sciences
66 rdf:type schema:DefinedTerm
67 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
68 schema:name Physical Chemistry (incl. Structural)
69 rdf:type schema:DefinedTerm
70 sg:journal.1015946 schema:issn 0095-9782
71 1572-8927
72 schema:name Journal of Solution Chemistry
73 rdf:type schema:Periodical
74 sg:person.01113450541.67 schema:affiliation https://www.grid.ac/institutes/grid.12155.32
75 schema:familyName Yperman
76 schema:givenName J.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01113450541.67
78 rdf:type schema:Person
79 sg:person.01176444520.19 schema:affiliation Nddcf8e4cff504ca889a8462ac0cde651
80 schema:familyName Luts
81 schema:givenName P.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01176444520.19
83 rdf:type schema:Person
84 sg:person.01244557720.16 schema:affiliation Nd4937f2af9f34be08733cf075ebbebf3
85 schema:familyName Vanhees
86 schema:givenName J.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01244557720.16
88 rdf:type schema:Person
89 sg:person.016377441051.16 schema:affiliation https://www.grid.ac/institutes/grid.12155.32
90 schema:familyName Van Poucke
91 schema:givenName L. C.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016377441051.16
93 rdf:type schema:Person
94 sg:person.0621537414.02 schema:affiliation https://www.grid.ac/institutes/grid.12155.32
95 schema:familyName Mullens
96 schema:givenName J.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0621537414.02
98 rdf:type schema:Person
99 sg:pub.10.1007/bf00647860 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001176177
100 https://doi.org/10.1007/bf00647860
101 rdf:type schema:CreativeWork
102 https://doi.org/10.1016/0022-1902(64)80257-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030473557
103 rdf:type schema:CreativeWork
104 https://doi.org/10.1021/cr60137a007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1054082752
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1021/j100820a012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055680374
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1021/ja01319a029 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055791815
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1021/ja01418a009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055798101
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1021/ja01626a015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055813885
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1246/bcsj.44.1515 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037514122
115 rdf:type schema:CreativeWork
116 https://www.grid.ac/institutes/grid.12155.32 schema:alternateName University of Hasselt
117 schema:name Laboratory of Inorganic and Physical Chemistry, Limburgs Universitair Centrum, B-3590, Diepenbeek, Belgium
118 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...