Chiral complex formers and agents for transphase transfer. Communication 3. Synthesis of podands with C2 symmetry and 24-crown-8-ether with D2 ... View Full Text


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Article Info

DATE

1988-03

AUTHORS

E. A. Él'perina, R. I. Abylgaziev, M. I. Struchkova, É. P. Serebryakov

ABSTRACT

ConclusionsPodands with C2 symmetry have been synthesized from 1,4;3,6-dianhydro-D-mannitol.Bis-(1,4;3,6-dianhydro-D-mannitol)-24-crown-6-ether with D2 symmetry has been synthesized.A convenient method of adding ethylene glycol segments of a polyether chain to a dianhydromannitol matrix has been developed; it proceeds via O-alkylation with 2-tetrahydro-pyranyloxy-1-bromoethane in superbasic medium and conversion of the reaction product.

PAGES

528-533

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00965372

DOI

http://dx.doi.org/10.1007/bf00965372

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017683112


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