Molecular structure of N,N′-bis(di-tert-butylphosphino)-N-trimethylsilylaminoiminophosphine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1985-10

AUTHORS

A. N. Chernega, M. Yu. Antipin, Yu. T. Struchkov, I. E. Bodeskul, E. O. Klebanskii, V. D. Romanenko

ABSTRACT

ConclusionsX-ray diffraction structural analysis established the structure and steric features of N,N′-bis(di-tert-butylphosphino)-N-trimethylsilylaminoiminophosphine, which is the first representative of dicoordinated phosphorus compounds with a bond system.The unshared electron pair at the phosphorus atom bound to the “iminyl” nitrogen atom is virtually unconjugated with the P=N bond. Stabilization of the P=N bond is a consequence of the steric shielding by the bulky substituents. More... »

PAGES

2068-2071

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00963235

DOI

http://dx.doi.org/10.1007/bf00963235

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047774006


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