Cation radicals of N,N1'-diarylbenzamidines View Full Text


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Article Info

DATE

1988-09

AUTHORS

E. P. Ivakhnenko, A. I. Prokof'ev, A. I. Shif, L. P. Olekhnovich, V. I. Minkin, M. I. Kabachnik

ABSTRACT

ConclusionsProtonation of N,N'-di-p-tolyl-(3,5-di-tert-butyl-4-oxylphenyl)amidinium radical leads to the formation of a cation radical similar in structure to amidinum salts with an s-cis and s-trans-arrangement of the p-tolyl groups relative to the phenoxyl group.Cation radicals formed by protonation of N,N'-di-p-tolyl-N-acetyl-(3,5-di-tertbutyl-4-oxyphenyl) amidinium and N,N-di-phenyl-N'-p-tolyl-(3,5-di-tert-butyl-4-oxylphenyl)amidinium radicals have a symmetric structure with inclusion of the carbonyl C atom and the phenyl ipso C atom in a four-membered 1,3-diazetidinium ring. More... »

PAGES

1896-1900

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00962509

DOI

http://dx.doi.org/10.1007/bf00962509

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1043573234


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