Simulation of donor-acceptor electron-transport systems in the example case of the oxidation of copper in media of organic solvents View Full Text


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Article Info

DATE

1991-06

AUTHORS

E. T. Épel'baum, V. I. Ponomarev, I. P. Lavrent'ev

ABSTRACT

The interaction of the onium salts [Me2Et=O]BF4−, [Me2=CH-OEt]BF4−, and [Me3=O]I− with metallic copper in DMSO, DMF, and acetonitrile (AN) has been investigated. It has been shown that the reaction takes place with an intermediate step involving the formation of Cu(I) compounds. The complexes [CuI(AN)4]BF4, [CuII(DMSO)5](BF4)2, [CuII(DMSO)4(AN)2](BF4)2, [CuII(DMSO)2(DMF)(AN)](BF4)2, and [ME3]3CuII4 · [Me3=O]I− have been isolated and characterized. It has been established that dipolar onium compounds which simulate the intermediate products of the interaction of the components of donor-acceptor electron-transport systems are responsible for the oxidation of metals in organic complex-forming media. More... »

PAGES

1167-1172

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00961290

DOI

http://dx.doi.org/10.1007/bf00961290

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003735379


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