Preparation and reactivity of metal-containing monomers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1990-04

AUTHORS

V. S. Savost'yanov, V. I. Ponomarev, A. D. Pomogailo, B. S. Seienova, I. N. Ivleva, A. G. Starikov, L. O. Atovmyan

ABSTRACT

We have obtained and characterized acrylamide complexes (AAm) of chlorides and nitrates of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), and Zn(II). We have shown that all the complexes of chlorides and also nitrates of Fe(III) and Cu(II) have the composition MXn·4AAm, while the complexes of Mn(II), Co(II), Ni(II), and Zn(II) contain water of crystallization and are characterized by the composition MXn·4AAm·2H2O. All the investigated complexes have an octahedral structure. In the example of the Co(II) nitrate complex we have established that coordination of the acrylamide occurs at the oxygen atom of the carbonyl group; in this case, the double bond is not touched. However, in the crystal we observe nonequivalence of the double bonds of the acrylamide groups. More... »

PAGES

674-679

Journal

TITLE

Russian Chemical Bulletin

ISSUE

4

VOLUME

39

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00960324

DOI

http://dx.doi.org/10.1007/bf00960324

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052653277


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Energy Problems in Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Filiate", 
            "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR", 
            "Rostov State Pedagogical Institute, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Savost'yanov", 
        "givenName": "V. S.", 
        "id": "sg:person.07602402447.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07602402447.31"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Energy Problems in Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Filiate", 
            "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR", 
            "Rostov State Pedagogical Institute, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ponomarev", 
        "givenName": "V. I.", 
        "id": "sg:person.010535710631.46", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010535710631.46"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Energy Problems in Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Filiate", 
            "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR", 
            "Rostov State Pedagogical Institute, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pomogailo", 
        "givenName": "A. D.", 
        "id": "sg:person.014522303673.99", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014522303673.99"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Energy Problems in Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Filiate", 
            "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR", 
            "Rostov State Pedagogical Institute, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Seienova", 
        "givenName": "B. S.", 
        "id": "sg:person.012430317413.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012430317413.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Energy Problems in Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Filiate", 
            "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR", 
            "Rostov State Pedagogical Institute, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ivleva", 
        "givenName": "I. N.", 
        "id": "sg:person.014267633742.24", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014267633742.24"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Energy Problems in Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Filiate", 
            "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR", 
            "Rostov State Pedagogical Institute, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Starikov", 
        "givenName": "A. G.", 
        "id": "sg:person.014454430517.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014454430517.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Energy Problems in Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Filiate", 
            "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR", 
            "Rostov State Pedagogical Institute, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Atovmyan", 
        "givenName": "L. O.", 
        "id": "sg:person.013606277777.39", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013606277777.39"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0020-1693(00)96010-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004769534"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/pol.1981.170190212", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1010795086"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-2852(61)90243-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013129170"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0020-1693(00)92540-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015245832"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0020-1693(00)92541-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044118306"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1990-04", 
    "datePublishedReg": "1990-04-01", 
    "description": "We have obtained and characterized acrylamide complexes (AAm) of chlorides and nitrates of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), and Zn(II). We have shown that all the complexes of chlorides and also nitrates of Fe(III) and Cu(II) have the composition MXn\u00b74AAm, while the complexes of Mn(II), Co(II), Ni(II), and Zn(II) contain water of crystallization and are characterized by the composition MXn\u00b74AAm\u00b72H2O. All the investigated complexes have an octahedral structure. In the example of the Co(II) nitrate complex we have established that coordination of the acrylamide occurs at the oxygen atom of the carbonyl group; in this case, the double bond is not touched. However, in the crystal we observe nonequivalence of the double bonds of the acrylamide groups.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00960324", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "39"
      }
    ], 
    "name": "Preparation and reactivity of metal-containing monomers", 
    "pagination": "674-679", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "face03748813be4cab73197a4ff1047fea1dec7f9dbb8c33c38ba30d0b21672f"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00960324"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1052653277"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00960324", 
      "https://app.dimensions.ai/details/publication/pub.1052653277"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T00:20", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8695_00000535.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF00960324"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00960324'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00960324'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00960324'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00960324'


 

This table displays all metadata directly associated to this object as RDF triples.

120 TRIPLES      21 PREDICATES      32 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00960324 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N796877be6fe947699c142945ab13d723
4 schema:citation https://doi.org/10.1002/pol.1981.170190212
5 https://doi.org/10.1016/0022-2852(61)90243-0
6 https://doi.org/10.1016/s0020-1693(00)92540-4
7 https://doi.org/10.1016/s0020-1693(00)92541-6
8 https://doi.org/10.1016/s0020-1693(00)96010-9
9 schema:datePublished 1990-04
10 schema:datePublishedReg 1990-04-01
11 schema:description We have obtained and characterized acrylamide complexes (AAm) of chlorides and nitrates of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), Cu(II), and Zn(II). We have shown that all the complexes of chlorides and also nitrates of Fe(III) and Cu(II) have the composition MXn·4AAm, while the complexes of Mn(II), Co(II), Ni(II), and Zn(II) contain water of crystallization and are characterized by the composition MXn·4AAm·2H2O. All the investigated complexes have an octahedral structure. In the example of the Co(II) nitrate complex we have established that coordination of the acrylamide occurs at the oxygen atom of the carbonyl group; in this case, the double bond is not touched. However, in the crystal we observe nonequivalence of the double bonds of the acrylamide groups.
12 schema:genre research_article
13 schema:inLanguage en
14 schema:isAccessibleForFree false
15 schema:isPartOf N393978a9640041fa9e6336dca3986ab1
16 Nf9e4b039940345a3ad87187f41e0f51d
17 sg:journal.1022309
18 schema:name Preparation and reactivity of metal-containing monomers
19 schema:pagination 674-679
20 schema:productId N06400749bfe64bb58a1a6829404ff3bb
21 Nad4b55a57c27486493c15220d5fc7b9d
22 Nc669dd4150c946629939a27f65572eed
23 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052653277
24 https://doi.org/10.1007/bf00960324
25 schema:sdDatePublished 2019-04-11T00:20
26 schema:sdLicense https://scigraph.springernature.com/explorer/license/
27 schema:sdPublisher N9299f7e14f334f0b87433cdbb415c7d6
28 schema:url http://link.springer.com/10.1007%2FBF00960324
29 sgo:license sg:explorer/license/
30 sgo:sdDataset articles
31 rdf:type schema:ScholarlyArticle
32 N06400749bfe64bb58a1a6829404ff3bb schema:name dimensions_id
33 schema:value pub.1052653277
34 rdf:type schema:PropertyValue
35 N393978a9640041fa9e6336dca3986ab1 schema:issueNumber 4
36 rdf:type schema:PublicationIssue
37 N69ee483b61b1496690a276788457c4ae rdf:first sg:person.012430317413.01
38 rdf:rest Nd10909dd1e7c4427b1da4ab4d0005ef1
39 N6bbb1662c3cd4a8f9941d8eddb7e59a9 rdf:first sg:person.013606277777.39
40 rdf:rest rdf:nil
41 N796877be6fe947699c142945ab13d723 rdf:first sg:person.07602402447.31
42 rdf:rest Nc637efa97fd6413f9f13dea62af188f8
43 N9299f7e14f334f0b87433cdbb415c7d6 schema:name Springer Nature - SN SciGraph project
44 rdf:type schema:Organization
45 Nad4b55a57c27486493c15220d5fc7b9d schema:name doi
46 schema:value 10.1007/bf00960324
47 rdf:type schema:PropertyValue
48 Nb30660cb171e43ff838d3e313c397561 rdf:first sg:person.014522303673.99
49 rdf:rest N69ee483b61b1496690a276788457c4ae
50 Nc637efa97fd6413f9f13dea62af188f8 rdf:first sg:person.010535710631.46
51 rdf:rest Nb30660cb171e43ff838d3e313c397561
52 Nc669dd4150c946629939a27f65572eed schema:name readcube_id
53 schema:value face03748813be4cab73197a4ff1047fea1dec7f9dbb8c33c38ba30d0b21672f
54 rdf:type schema:PropertyValue
55 Nd10909dd1e7c4427b1da4ab4d0005ef1 rdf:first sg:person.014267633742.24
56 rdf:rest Nf9b3ce5f5f6a4716b52ffeb06655a4d0
57 Nf9b3ce5f5f6a4716b52ffeb06655a4d0 rdf:first sg:person.014454430517.25
58 rdf:rest N6bbb1662c3cd4a8f9941d8eddb7e59a9
59 Nf9e4b039940345a3ad87187f41e0f51d schema:volumeNumber 39
60 rdf:type schema:PublicationVolume
61 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
62 schema:name Chemical Sciences
63 rdf:type schema:DefinedTerm
64 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
65 schema:name Inorganic Chemistry
66 rdf:type schema:DefinedTerm
67 sg:journal.1022309 schema:issn 1066-5285
68 1573-9171
69 schema:name Russian Chemical Bulletin
70 rdf:type schema:Periodical
71 sg:person.010535710631.46 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
72 schema:familyName Ponomarev
73 schema:givenName V. I.
74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010535710631.46
75 rdf:type schema:Person
76 sg:person.012430317413.01 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
77 schema:familyName Seienova
78 schema:givenName B. S.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012430317413.01
80 rdf:type schema:Person
81 sg:person.013606277777.39 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
82 schema:familyName Atovmyan
83 schema:givenName L. O.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013606277777.39
85 rdf:type schema:Person
86 sg:person.014267633742.24 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
87 schema:familyName Ivleva
88 schema:givenName I. N.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014267633742.24
90 rdf:type schema:Person
91 sg:person.014454430517.25 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
92 schema:familyName Starikov
93 schema:givenName A. G.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014454430517.25
95 rdf:type schema:Person
96 sg:person.014522303673.99 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
97 schema:familyName Pomogailo
98 schema:givenName A. D.
99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014522303673.99
100 rdf:type schema:Person
101 sg:person.07602402447.31 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
102 schema:familyName Savost'yanov
103 schema:givenName V. S.
104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07602402447.31
105 rdf:type schema:Person
106 https://doi.org/10.1002/pol.1981.170190212 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010795086
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1016/0022-2852(61)90243-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013129170
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1016/s0020-1693(00)92540-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015245832
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1016/s0020-1693(00)92541-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044118306
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1016/s0020-1693(00)96010-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004769534
115 rdf:type schema:CreativeWork
116 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
117 schema:name Institute of Energy Problems in Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Filiate
118 N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka Branch, USSR
119 Rostov State Pedagogical Institute, USSR
120 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...