Behavior of adamantane and its functional derivatives on chemical ionization View Full Text


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Article Info

DATE

1987-09

AUTHORS

V. I. Kadentsev, O. S. Chizhov, N. G. Kolotyrkina, S. D. Isaev, O. F. Kozlov, A. G. Yurchenko

ABSTRACT

ConclusionsUnder chemical ionization conditions, adamantane forms the ions M+. and [M-H]+, while 2,4-dehydroadamantane also gives protonated ([M + H]+) and alkylated ([M + Alk]+) ions.Functional groups in the adamantane molecule undergo ready alkylation and protonation, and may be lost as the HX molecule. Protonation of the diazirine group results in the loss of a molecule of nitrogen. The diazirine group is protonated more readily than the hydroxyl group, but less readily than CN, CONH2, or COOCH3. More... »

PAGES

1862-1867

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00958331

DOI

http://dx.doi.org/10.1007/bf00958331

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011836669


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