Synthesis of polymeric phosphinocarborane complexes of Rh(I) and their catalytic properties in olefin and diene hydrogenation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1985-11

AUTHORS

V. N. Kalinin, O. A. Mel'nik, A. A. Sakharova, T. M. Frunze, L. I. Zakharkin, N. V. Borunova, V. Z. Sharf

ABSTRACT

ConclusionsA method has been developed for the synthesis of polymeric phosphinocarborane complexes of rhodium(I), based on copolymerization of methyl methacrylate with salts of 1-isopropenyl(3)-1,2-dicarbaundecaborate and subsequent interaction of the resulting polymeric matrix with tris(triphenylphosphine)rhodium chloride.It has been shown that the phosphinocarborane complexes of rhodium(I) have high activities in the hydrogenation and isomerization of olefins and diolefins. More... »

PAGES

2258-2263

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00956779

DOI

http://dx.doi.org/10.1007/bf00956779

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030361677


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