2-alkoxy-3,6-di-tert-butylphenoxyls View Full Text


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Article Info

DATE

1985-06

AUTHORS

T. I. Prokof'eva, A. I. Prokof'ev, V. B. Vol'eva, V. V. Ershov, M. I. Kabachnik

ABSTRACT

ConclusionsIn the 3,6-di-tert-butyl-2-R-hydroxyphenoxyl radicals containing a sp3-hybridized carbon atom as the central atom there are no carbotropic transitions on the EPR time scale because of the impossibility of localization of the unpaired electron on the central atom.Addition of acids leads to the acidolysis of the CO bond of the carbon fragment with the free radical ligand and the formation of a cation-radical, in which carbotropic transitions take place. More... »

PAGES

1212-1218

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00956086

DOI

http://dx.doi.org/10.1007/bf00956086

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1021251797


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