Ontology type: schema:ScholarlyArticle
1989-05
AUTHORSL. I. Mazaletskaya, G. V. Karpukhina, G. G. Lazarev, A. I. Prokofev, N. L. Komissarova, I. S. Belostotskaya, V. V. Ershov
ABSTRACTConclusions3,6-Di-tert-butyl-2-hydroxyphenoxyl radicals (QH.) were detected by EPR spectroscopy in a mixture of 3,6-di-tert-butylpyrocatechol (QH2) and 3,6-di-tert-butyl-1,2-benzoquinone (Q) in the polymerization of methyl methacrylate. The rate constant for the reaction QH2 + Q⇄ 2QH. and the rate contants for the forward and back reactions were determined at 60°C.
PAGES1081-1083
http://scigraph.springernature.com/pub.10.1007/bf00955457
DOIhttp://dx.doi.org/10.1007/bf00955457
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1049587012
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow",
"id": "http://www.grid.ac/institutes/grid.424930.8",
"name": [
"N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
],
"type": "Organization"
},
"familyName": "Mazaletskaya",
"givenName": "L. I.",
"id": "sg:person.016013464523.07",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016013464523.07"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow",
"id": "http://www.grid.ac/institutes/grid.424930.8",
"name": [
"N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
],
"type": "Organization"
},
"familyName": "Karpukhina",
"givenName": "G. V.",
"id": "sg:person.010034262415.73",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010034262415.73"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow",
"id": "http://www.grid.ac/institutes/grid.424930.8",
"name": [
"N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
],
"type": "Organization"
},
"familyName": "Lazarev",
"givenName": "G. G.",
"id": "sg:person.012632621357.19",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012632621357.19"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow",
"id": "http://www.grid.ac/institutes/grid.424930.8",
"name": [
"N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
],
"type": "Organization"
},
"familyName": "Prokofev",
"givenName": "A. I.",
"id": "sg:person.011205575207.14",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011205575207.14"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow",
"id": "http://www.grid.ac/institutes/grid.424930.8",
"name": [
"N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
],
"type": "Organization"
},
"familyName": "Komissarova",
"givenName": "N. L.",
"id": "sg:person.016121506364.44",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016121506364.44"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow",
"id": "http://www.grid.ac/institutes/grid.424930.8",
"name": [
"N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
],
"type": "Organization"
},
"familyName": "Belostotskaya",
"givenName": "I. S.",
"id": "sg:person.015523023503.99",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015523023503.99"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow",
"id": "http://www.grid.ac/institutes/grid.424930.8",
"name": [
"N. N. Semenov Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
],
"type": "Organization"
},
"familyName": "Ershov",
"givenName": "V. V.",
"id": "sg:person.010414742241.10",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010414742241.10"
],
"type": "Person"
}
],
"datePublished": "1989-05",
"datePublishedReg": "1989-05-01",
"description": "Conclusions3,6-Di-tert-butyl-2-hydroxyphenoxyl radicals (QH.) were detected by EPR spectroscopy in a mixture of 3,6-di-tert-butylpyrocatechol (QH2) and 3,6-di-tert-butyl-1,2-benzoquinone (Q) in the polymerization of methyl methacrylate. The rate constant for the reaction QH2 + Q\u21c4 2QH. and the rate contants for the forward and back reactions were determined at 60\u00b0C.",
"genre": "article",
"id": "sg:pub.10.1007/bf00955457",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1022309",
"issn": [
"1026-3500",
"1066-5285"
],
"name": "Russian Chemical Bulletin",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "5",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "38"
}
],
"keywords": [
"hydroxyphenoxyl radicals",
"methyl methacrylate",
"inhibition of polymerization",
"EPR spectroscopy",
"rate contants",
"polymerization",
"back reaction",
"methacrylate",
"benzoquinone",
"radicals",
"spectroscopy",
"QH2",
"reaction",
"di",
"mixture",
"contants",
"formation",
"system",
"inhibition",
"rate"
],
"name": "Formation of 3,6-di-tert-butyl-2-hydroxyphenoxyl radicals upon the inhibition of polymerization of methyl methacrylate by the system containing 3,6-di-tert-butylpryocatechol and 3,6-di-tert-butyl-1,2-benzoquinone",
"pagination": "1081-1083",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1049587012"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf00955457"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf00955457",
"https://app.dimensions.ai/details/publication/pub.1049587012"
],
"sdDataset": "articles",
"sdDatePublished": "2022-05-10T09:44",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220509/entities/gbq_results/article/article_191.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/bf00955457"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00955457'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00955457'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00955457'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00955457'
This table displays all metadata directly associated to this object as RDF triples.
120 TRIPLES
21 PREDICATES
46 URIs
38 LITERALS
6 BLANK NODES