Kinetic mechanisms of polymerization of butyl acrylate in the presence of porphyrin cobalt during induction View Full Text


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Article Info

DATE

1983-09

AUTHORS

A. G. Oganova, B. R. Smirnov, N. T. Ioffe, N. S. Enikolopyan

ABSTRACT

ConclusionsThe kinetic parameters of polymerization (PM) of butyl acrylate (BA) in the presence of porphyrin cobalts (CoP) fit into the general scheme of radical polymerization in the presence of chain-transfer catalysts.The study of the kinetic mechanisms of PM of BA in the induction period showed that accumulation of macroradicals takes place more rapidly than in the case of irreversible inhibition. This is in agreement with the hypothesis that the process of inhibition of PM of BA by CoP is “reversible.”Some kinetic parameters of this process were estimated based on the proposed kinetic scheme. More... »

PAGES

1837-1842

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00954657

DOI

http://dx.doi.org/10.1007/bf00954657

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032836788


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