State of cobalt included in the layer structure of silica and effect of the structure of cobalt-containing sites on the ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1986-08

AUTHORS

M. V. Tsodikov, Ya. R. Katsobashvili, G. A. Korneeva, O. G. Ellert, V. M. Novotortsev

ABSTRACT

Isolated cobalt (II) ions in octa- and tetrahedral coordination environments are included in the structure of the matrix in application of dicobalt octacarbonyl on a matrix of layered silica.The effect of hydrogen or synthesis gas on the cobalt (II) included in the matrix results in an increase in the concentration of cobalt in tetrahedral coordination, distortion of the octahedral structure of divalent cobalt, subsequent loss of ligands, and the formation of metallic cobalt. Isolated cobalt (II) ions in octa- and tetrahedral coordination environments are included in the structure of the matrix in application of dicobalt octacarbonyl on a matrix of layered silica. The effect of hydrogen or synthesis gas on the cobalt (II) included in the matrix results in an increase in the concentration of cobalt in tetrahedral coordination, distortion of the octahedral structure of divalent cobalt, subsequent loss of ligands, and the formation of metallic cobalt. More... »

PAGES

1564-1568

Journal

TITLE

Russian Chemical Bulletin

ISSUE

8

VOLUME

35

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00954586

DOI

http://dx.doi.org/10.1007/bf00954586

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012992131


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