Acidoligand substitution in large palladium clusters View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1989-04

AUTHORS

V. P. Zagorodnikov, M. N. Vargaftik, D. I. Kochubei, V. A. Likholobov, V. N. Kolomiichuk, A. N. Naumochkin, A. L. Chuvilin, V. M. Novotortsev, O. G. éllert, I. I. Moiseev

ABSTRACT

In an aqueous solution of potassium hexafluorophosphate, the outer-sphere acetate anions in the large cluster with the idealized formula Pd561 Phen60(OAc)180 (Phen=1,10-phenanthroline) are completely replaced by outer-sphere hexafluorophosphate anions and coordinated oxide anions.Upon substitution of the acetate ligands, the icosahedral packing of the palladium atoms in the metal framework of the large cluster is preserved, but the distance between atoms in the outer layer increases substantially. In an aqueous solution of potassium hexafluorophosphate, the outer-sphere acetate anions in the large cluster with the idealized formula Pd561 Phen60(OAc)180 (Phen=1,10-phenanthroline) are completely replaced by outer-sphere hexafluorophosphate anions and coordinated oxide anions. Upon substitution of the acetate ligands, the icosahedral packing of the palladium atoms in the metal framework of the large cluster is preserved, but the distance between atoms in the outer layer increases substantially. More... »

PAGES

762-766

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00953288

DOI

http://dx.doi.org/10.1007/bf00953288

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1010175216


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow", 
            "Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zagorodnikov", 
        "givenName": "V. P.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow", 
            "Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vargaftik", 
        "givenName": "M. N.", 
        "id": "sg:person.010466133005.43", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010466133005.43"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow", 
            "Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kochubei", 
        "givenName": "D. I.", 
        "id": "sg:person.014770054431.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014770054431.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow", 
            "Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Likholobov", 
        "givenName": "V. A.", 
        "id": "sg:person.011776663725.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011776663725.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow", 
            "Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kolomiichuk", 
        "givenName": "V. N.", 
        "id": "sg:person.07716616361.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07716616361.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow", 
            "Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Naumochkin", 
        "givenName": "A. N.", 
        "id": "sg:person.012617663450.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012617663450.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow", 
            "Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chuvilin", 
        "givenName": "A. L.", 
        "id": "sg:person.0650575373.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0650575373.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow", 
            "Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Novotortsev", 
        "givenName": "V. M.", 
        "id": "sg:person.01013744635.03", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01013744635.03"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow", 
            "Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "\u00e9llert", 
        "givenName": "O. G.", 
        "id": "sg:person.013257066722.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013257066722.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Boreskov Institute of Catalysis", 
          "id": "https://www.grid.ac/institutes/grid.418421.a", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow", 
            "Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Moiseev", 
        "givenName": "I. I.", 
        "id": "sg:person.07505356441.41", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07505356441.41"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0022-328x(86)80022-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026715633"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c39850000937", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038306999"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00505a003", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055737840"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1989-04", 
    "datePublishedReg": "1989-04-01", 
    "description": "In an aqueous solution of potassium hexafluorophosphate, the outer-sphere acetate anions in the large cluster with the idealized formula Pd561 Phen60(OAc)180 (Phen=1,10-phenanthroline) are completely replaced by outer-sphere hexafluorophosphate anions and coordinated oxide anions.Upon substitution of the acetate ligands, the icosahedral packing of the palladium atoms in the metal framework of the large cluster is preserved, but the distance between atoms in the outer layer increases substantially. In an aqueous solution of potassium hexafluorophosphate, the outer-sphere acetate anions in the large cluster with the idealized formula Pd561 Phen60(OAc)180 (Phen=1,10-phenanthroline) are completely replaced by outer-sphere hexafluorophosphate anions and coordinated oxide anions. Upon substitution of the acetate ligands, the icosahedral packing of the palladium atoms in the metal framework of the large cluster is preserved, but the distance between atoms in the outer layer increases substantially.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00953288", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "38"
      }
    ], 
    "name": "Acidoligand substitution in large palladium clusters", 
    "pagination": "762-766", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "3079d90f551787532ea910c89a1173cc9546e3d760c98b060fc065cb8cd657f3"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00953288"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1010175216"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00953288", 
      "https://app.dimensions.ai/details/publication/pub.1010175216"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T13:33", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000370_0000000370/records_46769_00000000.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF00953288"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00953288'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00953288'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00953288'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00953288'


 

This table displays all metadata directly associated to this object as RDF triples.

133 TRIPLES      21 PREDICATES      30 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00953288 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author Need1364be46c4ceca5f4e90326a7cedc
4 schema:citation https://doi.org/10.1016/0022-328x(86)80022-5
5 https://doi.org/10.1021/ja00505a003
6 https://doi.org/10.1039/c39850000937
7 schema:datePublished 1989-04
8 schema:datePublishedReg 1989-04-01
9 schema:description In an aqueous solution of potassium hexafluorophosphate, the outer-sphere acetate anions in the large cluster with the idealized formula Pd561 Phen60(OAc)180 (Phen=1,10-phenanthroline) are completely replaced by outer-sphere hexafluorophosphate anions and coordinated oxide anions.Upon substitution of the acetate ligands, the icosahedral packing of the palladium atoms in the metal framework of the large cluster is preserved, but the distance between atoms in the outer layer increases substantially. In an aqueous solution of potassium hexafluorophosphate, the outer-sphere acetate anions in the large cluster with the idealized formula Pd561 Phen60(OAc)180 (Phen=1,10-phenanthroline) are completely replaced by outer-sphere hexafluorophosphate anions and coordinated oxide anions. Upon substitution of the acetate ligands, the icosahedral packing of the palladium atoms in the metal framework of the large cluster is preserved, but the distance between atoms in the outer layer increases substantially.
10 schema:genre research_article
11 schema:inLanguage en
12 schema:isAccessibleForFree false
13 schema:isPartOf Nab3821bb9ada473ab1b6a23ad7b37b52
14 Nb9882d54bc214f47972d2d21705ce05d
15 sg:journal.1022309
16 schema:name Acidoligand substitution in large palladium clusters
17 schema:pagination 762-766
18 schema:productId N3a33d6f6691d4017a6c615ca9007969a
19 N9396dbb4ca3542bf98c2c7d1d2eb434e
20 Nd625f7794bff44d480d3455c6dcdd500
21 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010175216
22 https://doi.org/10.1007/bf00953288
23 schema:sdDatePublished 2019-04-11T13:33
24 schema:sdLicense https://scigraph.springernature.com/explorer/license/
25 schema:sdPublisher N171f1fd150da4e5d8d151145f86aed2b
26 schema:url http://link.springer.com/10.1007%2FBF00953288
27 sgo:license sg:explorer/license/
28 sgo:sdDataset articles
29 rdf:type schema:ScholarlyArticle
30 N151702bd3ab14229a2a54591a332d1d6 rdf:first sg:person.010466133005.43
31 rdf:rest Ne4db2173236240a090391ee4962ee493
32 N171f1fd150da4e5d8d151145f86aed2b schema:name Springer Nature - SN SciGraph project
33 rdf:type schema:Organization
34 N341a8919515f415486b61229741b8501 rdf:first sg:person.07505356441.41
35 rdf:rest rdf:nil
36 N3a33d6f6691d4017a6c615ca9007969a schema:name readcube_id
37 schema:value 3079d90f551787532ea910c89a1173cc9546e3d760c98b060fc065cb8cd657f3
38 rdf:type schema:PropertyValue
39 N48b596cba7d949dd9f92b9cfb3b92583 rdf:first sg:person.0650575373.28
40 rdf:rest Na24dcaa607ee4cc78a5eb071ac47dbd6
41 N9396dbb4ca3542bf98c2c7d1d2eb434e schema:name dimensions_id
42 schema:value pub.1010175216
43 rdf:type schema:PropertyValue
44 N9609150a1e084e6c9e43a54ab0ed3ca3 rdf:first sg:person.013257066722.09
45 rdf:rest N341a8919515f415486b61229741b8501
46 Na24dcaa607ee4cc78a5eb071ac47dbd6 rdf:first sg:person.01013744635.03
47 rdf:rest N9609150a1e084e6c9e43a54ab0ed3ca3
48 Nab3821bb9ada473ab1b6a23ad7b37b52 schema:issueNumber 4
49 rdf:type schema:PublicationIssue
50 Nb33ffe5a9e274f8ba53bc48333a29e12 rdf:first sg:person.011776663725.01
51 rdf:rest Nb5beab4541c448a2bca851eba9405a5a
52 Nb5beab4541c448a2bca851eba9405a5a rdf:first sg:person.07716616361.25
53 rdf:rest Nf0dd38150a6d4f6181a5132b3c08e750
54 Nb9882d54bc214f47972d2d21705ce05d schema:volumeNumber 38
55 rdf:type schema:PublicationVolume
56 Nd625f7794bff44d480d3455c6dcdd500 schema:name doi
57 schema:value 10.1007/bf00953288
58 rdf:type schema:PropertyValue
59 Ne4db2173236240a090391ee4962ee493 rdf:first sg:person.014770054431.55
60 rdf:rest Nb33ffe5a9e274f8ba53bc48333a29e12
61 Need1364be46c4ceca5f4e90326a7cedc rdf:first Nf54848bd031a465ca389be9f03abfa47
62 rdf:rest N151702bd3ab14229a2a54591a332d1d6
63 Nf0dd38150a6d4f6181a5132b3c08e750 rdf:first sg:person.012617663450.37
64 rdf:rest N48b596cba7d949dd9f92b9cfb3b92583
65 Nf54848bd031a465ca389be9f03abfa47 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
66 schema:familyName Zagorodnikov
67 schema:givenName V. P.
68 rdf:type schema:Person
69 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
70 schema:name Chemical Sciences
71 rdf:type schema:DefinedTerm
72 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
73 schema:name Inorganic Chemistry
74 rdf:type schema:DefinedTerm
75 sg:journal.1022309 schema:issn 1066-5285
76 1573-9171
77 schema:name Russian Chemical Bulletin
78 rdf:type schema:Periodical
79 sg:person.01013744635.03 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
80 schema:familyName Novotortsev
81 schema:givenName V. M.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01013744635.03
83 rdf:type schema:Person
84 sg:person.010466133005.43 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
85 schema:familyName Vargaftik
86 schema:givenName M. N.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010466133005.43
88 rdf:type schema:Person
89 sg:person.011776663725.01 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
90 schema:familyName Likholobov
91 schema:givenName V. A.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011776663725.01
93 rdf:type schema:Person
94 sg:person.012617663450.37 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
95 schema:familyName Naumochkin
96 schema:givenName A. N.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012617663450.37
98 rdf:type schema:Person
99 sg:person.013257066722.09 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
100 schema:familyName éllert
101 schema:givenName O. G.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013257066722.09
103 rdf:type schema:Person
104 sg:person.014770054431.55 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
105 schema:familyName Kochubei
106 schema:givenName D. I.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014770054431.55
108 rdf:type schema:Person
109 sg:person.0650575373.28 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
110 schema:familyName Chuvilin
111 schema:givenName A. L.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0650575373.28
113 rdf:type schema:Person
114 sg:person.07505356441.41 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
115 schema:familyName Moiseev
116 schema:givenName I. I.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07505356441.41
118 rdf:type schema:Person
119 sg:person.07716616361.25 schema:affiliation https://www.grid.ac/institutes/grid.418421.a
120 schema:familyName Kolomiichuk
121 schema:givenName V. N.
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07716616361.25
123 rdf:type schema:Person
124 https://doi.org/10.1016/0022-328x(86)80022-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026715633
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1021/ja00505a003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055737840
127 rdf:type schema:CreativeWork
128 https://doi.org/10.1039/c39850000937 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038306999
129 rdf:type schema:CreativeWork
130 https://www.grid.ac/institutes/grid.418421.a schema:alternateName Boreskov Institute of Catalysis
131 schema:name Institute of Catalysis, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk
132 N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, Moscow
133 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...