Study of the catalytic activity of metal complexes fixed on solid supports. 7. Synthesis of Pd-Sn complexes attached to macroporous ... View Full Text


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Article Info

DATE

1989-04

AUTHORS

V. Z. Sharf, L. D. Panfilova, N. V. Borunova, N. V. Antseva, L. P. Karapetyan, P. G. Antonov, K. M. Saldadze

ABSTRACT

ConclusionsNew catalysts, Pd-Sn compounds, were synthesized and fixed to macroporous anion exchangers. They are active in hydrogenation and isomerization reactions of 1-hexene.The catalytic properties of the Pd-Sn systems depends on the structure of the fixed compound (cluster, complex), the nature and state of the exchanger functional groups (Cl-or OH-form), and the reaction conditions (pH, PH2).The cluster [Pd4(SnCl2)2(SnCl3)8]5− on the highly basic anion exchanger AV-17-2P (Cl-form) catalyzes mainly the hydrogenation reaction, while the complex [Pd(SnCl3)4]2− catalyzes the isomerization reaction.The complex [Pd(SnCl34)]2−, fixed to the weakly basic anion exchanger AN-221 (OH-form), is active in the isomerization and hydrogenation of 1-hexene under mild conditions. More... »

PAGES

695-698

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00953271

DOI

http://dx.doi.org/10.1007/bf00953271

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017543791


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