Halogenation of 3,6-di-tert-butylpyrocatechol with retention of the alkyl substituents View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1983-06

AUTHORS

V. B. Vol'eva, I. A. Novikova, I. S. Belostotskaya, É. V. Dzhuaryan, V. V. Ershov

ABSTRACT

Conclusions3,6-Di-tert-butylpyrocatechol can be brominated and chlorinated with retention of the tert-butyl groups.The yield of the 4-bromo-3,6-di-tert-butylpyrocatechol that is formed during bromination is quite dependent on the nature of the solvent and the character of the counterion in the composition of the intermediate σ complex.

PAGES

1285-1288

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00953176

DOI

http://dx.doi.org/10.1007/bf00953176

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037161197


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow", 
          "id": "http://www.grid.ac/institutes/grid.424930.8", 
          "name": [
            "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vol'eva", 
        "givenName": "V. B.", 
        "id": "sg:person.014515631207.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014515631207.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow", 
          "id": "http://www.grid.ac/institutes/grid.424930.8", 
          "name": [
            "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Novikova", 
        "givenName": "I. A.", 
        "id": "sg:person.012115613077.26", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012115613077.26"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow", 
          "id": "http://www.grid.ac/institutes/grid.424930.8", 
          "name": [
            "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Belostotskaya", 
        "givenName": "I. S.", 
        "id": "sg:person.015523023503.99", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015523023503.99"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow", 
          "id": "http://www.grid.ac/institutes/grid.424930.8", 
          "name": [
            "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dzhuaryan", 
        "givenName": "\u00c9. V.", 
        "id": "sg:person.015531125641.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015531125641.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow", 
          "id": "http://www.grid.ac/institutes/grid.424930.8", 
          "name": [
            "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ershov", 
        "givenName": "V. V.", 
        "id": "sg:person.010414742241.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010414742241.10"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1038/1821300a0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040378978", 
          "https://doi.org/10.1038/1821300a0"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1983-06", 
    "datePublishedReg": "1983-06-01", 
    "description": "Conclusions3,6-Di-tert-butylpyrocatechol can be brominated and chlorinated with retention of the tert-butyl groups.The yield of the 4-bromo-3,6-di-tert-butylpyrocatechol that is formed during bromination is quite dependent on the nature of the solvent and the character of the counterion in the composition of the intermediate \u03c3 complex.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00953176", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1026-3500", 
          "1066-5285"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "32"
      }
    ], 
    "keywords": [
      "di-tert", 
      "tert-butyl group", 
      "alkyl substituents", 
      "butylpyrocatechol", 
      "retention", 
      "group", 
      "bromination", 
      "solvent", 
      "counterions", 
      "complexes", 
      "halogenation", 
      "substituents", 
      "yield", 
      "composition", 
      "nature", 
      "character"
    ], 
    "name": "Halogenation of 3,6-di-tert-butylpyrocatechol with retention of the alkyl substituents", 
    "pagination": "1285-1288", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1037161197"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00953176"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00953176", 
      "https://app.dimensions.ai/details/publication/pub.1037161197"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-10T09:41", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220509/entities/gbq_results/article/article_166.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00953176"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00953176'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00953176'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00953176'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00953176'


 

This table displays all metadata directly associated to this object as RDF triples.

102 TRIPLES      22 PREDICATES      42 URIs      34 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00953176 schema:about anzsrc-for:03
2 schema:author N23bb08a481784e83b46b2e4cb8da8e40
3 schema:citation sg:pub.10.1038/1821300a0
4 schema:datePublished 1983-06
5 schema:datePublishedReg 1983-06-01
6 schema:description Conclusions3,6-Di-tert-butylpyrocatechol can be brominated and chlorinated with retention of the tert-butyl groups.The yield of the 4-bromo-3,6-di-tert-butylpyrocatechol that is formed during bromination is quite dependent on the nature of the solvent and the character of the counterion in the composition of the intermediate σ complex.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N31d608156e4d4363bdf06f6fb53cd815
11 Ncf1cfff8c59a4286bd04955b60f21673
12 sg:journal.1022309
13 schema:keywords alkyl substituents
14 bromination
15 butylpyrocatechol
16 character
17 complexes
18 composition
19 counterions
20 di-tert
21 group
22 halogenation
23 nature
24 retention
25 solvent
26 substituents
27 tert-butyl group
28 yield
29 schema:name Halogenation of 3,6-di-tert-butylpyrocatechol with retention of the alkyl substituents
30 schema:pagination 1285-1288
31 schema:productId N4c5347862f254c819af83bdb957fb910
32 N65cad7723cbc410fa2e77249eab1ecf0
33 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037161197
34 https://doi.org/10.1007/bf00953176
35 schema:sdDatePublished 2022-05-10T09:41
36 schema:sdLicense https://scigraph.springernature.com/explorer/license/
37 schema:sdPublisher N932b9af113be4309991410e44ffef230
38 schema:url https://doi.org/10.1007/bf00953176
39 sgo:license sg:explorer/license/
40 sgo:sdDataset articles
41 rdf:type schema:ScholarlyArticle
42 N1def3bde6f2341be8a245cbe5f58ed5f rdf:first sg:person.015523023503.99
43 rdf:rest Nc91cba8c1a0b489aa4d8e486f020853c
44 N211c1b5bebd14f409048de67147bb0f3 rdf:first sg:person.012115613077.26
45 rdf:rest N1def3bde6f2341be8a245cbe5f58ed5f
46 N23bb08a481784e83b46b2e4cb8da8e40 rdf:first sg:person.014515631207.10
47 rdf:rest N211c1b5bebd14f409048de67147bb0f3
48 N31d608156e4d4363bdf06f6fb53cd815 schema:volumeNumber 32
49 rdf:type schema:PublicationVolume
50 N4c5347862f254c819af83bdb957fb910 schema:name doi
51 schema:value 10.1007/bf00953176
52 rdf:type schema:PropertyValue
53 N65cad7723cbc410fa2e77249eab1ecf0 schema:name dimensions_id
54 schema:value pub.1037161197
55 rdf:type schema:PropertyValue
56 N777ad6bf1ebf4310814ba0e8a7e6ce9d rdf:first sg:person.010414742241.10
57 rdf:rest rdf:nil
58 N932b9af113be4309991410e44ffef230 schema:name Springer Nature - SN SciGraph project
59 rdf:type schema:Organization
60 Nc91cba8c1a0b489aa4d8e486f020853c rdf:first sg:person.015531125641.09
61 rdf:rest N777ad6bf1ebf4310814ba0e8a7e6ce9d
62 Ncf1cfff8c59a4286bd04955b60f21673 schema:issueNumber 6
63 rdf:type schema:PublicationIssue
64 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
65 schema:name Chemical Sciences
66 rdf:type schema:DefinedTerm
67 sg:journal.1022309 schema:issn 1026-3500
68 1066-5285
69 schema:name Russian Chemical Bulletin
70 schema:publisher Springer Nature
71 rdf:type schema:Periodical
72 sg:person.010414742241.10 schema:affiliation grid-institutes:grid.424930.8
73 schema:familyName Ershov
74 schema:givenName V. V.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010414742241.10
76 rdf:type schema:Person
77 sg:person.012115613077.26 schema:affiliation grid-institutes:grid.424930.8
78 schema:familyName Novikova
79 schema:givenName I. A.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012115613077.26
81 rdf:type schema:Person
82 sg:person.014515631207.10 schema:affiliation grid-institutes:grid.424930.8
83 schema:familyName Vol'eva
84 schema:givenName V. B.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014515631207.10
86 rdf:type schema:Person
87 sg:person.015523023503.99 schema:affiliation grid-institutes:grid.424930.8
88 schema:familyName Belostotskaya
89 schema:givenName I. S.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015523023503.99
91 rdf:type schema:Person
92 sg:person.015531125641.09 schema:affiliation grid-institutes:grid.424930.8
93 schema:familyName Dzhuaryan
94 schema:givenName É. V.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015531125641.09
96 rdf:type schema:Person
97 sg:pub.10.1038/1821300a0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040378978
98 https://doi.org/10.1038/1821300a0
99 rdf:type schema:CreativeWork
100 grid-institutes:grid.424930.8 schema:alternateName Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow
101 schema:name Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow
102 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...