Dienone-phenol conversions of 4-x-substituted 4-hydroxy-2,6-di-tert-butylcyclohexa-2,5-dienones in acid media View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1983-03

AUTHORS

R. D. Malysheva, V. V. Ershov, A. A. Volod'kin

ABSTRACT

ConclusionsIt has been established using as examples the interaction of 4-ethyl-4-isopropyl-, 4-tert-butyl-, and 4-(γ-hydroxypropyl)-4-hydroxy-2,6-di-tert-butylcyclohexa-2,5-dienones (quinols) with acetic anhydride and with hydrogen chloride in methanol that replacement of a tertiary butyl group by the nucleophile occurs in the process of acid decomposition.Reaction of 4-methyl-4-hydroxy-2,6-di-tert-butylcyclohexane-2,5-dienone with acetic anhydride and with hydrogen chloride in methanol occurs in a specific manner due to the formation of activated 2,6-di-tert-butylmethylenequinone in the reaction process. More... »

PAGES

550-552

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00953095

DOI

http://dx.doi.org/10.1007/bf00953095

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002367554


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow", 
          "id": "http://www.grid.ac/institutes/grid.424930.8", 
          "name": [
            "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Malysheva", 
        "givenName": "R. D.", 
        "id": "sg:person.013375177735.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013375177735.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow", 
          "id": "http://www.grid.ac/institutes/grid.424930.8", 
          "name": [
            "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ershov", 
        "givenName": "V. V.", 
        "id": "sg:person.010414742241.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010414742241.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow", 
          "id": "http://www.grid.ac/institutes/grid.424930.8", 
          "name": [
            "Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Volod'kin", 
        "givenName": "A. A.", 
        "id": "sg:person.012407113573.82", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012407113573.82"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1983-03", 
    "datePublishedReg": "1983-03-01", 
    "description": "ConclusionsIt has been established using as examples the interaction of 4-ethyl-4-isopropyl-, 4-tert-butyl-, and 4-(\u03b3-hydroxypropyl)-4-hydroxy-2,6-di-tert-butylcyclohexa-2,5-dienones (quinols) with acetic anhydride and with hydrogen chloride in methanol that replacement of a tertiary butyl group by the nucleophile occurs in the process of acid decomposition.Reaction of 4-methyl-4-hydroxy-2,6-di-tert-butylcyclohexane-2,5-dienone with acetic anhydride and with hydrogen chloride in methanol occurs in a specific manner due to the formation of activated 2,6-di-tert-butylmethylenequinone in the reaction process.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00953095", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1026-3500", 
          "1066-5285"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "32"
      }
    ], 
    "keywords": [
      "specific manner", 
      "reaction process", 
      "ConclusionsIt", 
      "hydrogen chloride", 
      "group", 
      "replacement", 
      "acid decomposition", 
      "manner", 
      "acid medium", 
      "process", 
      "hydroxy", 
      "anhydride", 
      "chloride", 
      "methanol", 
      "decomposition", 
      "acetic anhydride", 
      "tertiary butyl group", 
      "reaction", 
      "conversion", 
      "example", 
      "interaction", 
      "formation", 
      "medium", 
      "butylcyclohexane", 
      "di-tert", 
      "butyl groups", 
      "dienone", 
      "butylcyclohexa", 
      "nucleophiles"
    ], 
    "name": "Dienone-phenol conversions of 4-x-substituted 4-hydroxy-2,6-di-tert-butylcyclohexa-2,5-dienones in acid media", 
    "pagination": "550-552", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1002367554"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00953095"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00953095", 
      "https://app.dimensions.ai/details/publication/pub.1002367554"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-10T09:41", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220509/entities/gbq_results/article/article_171.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00953095"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00953095'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00953095'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00953095'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00953095'


 

This table displays all metadata directly associated to this object as RDF triples.

101 TRIPLES      21 PREDICATES      55 URIs      47 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00953095 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N16ed4754f70a493090ca96e03cf74e6a
4 schema:datePublished 1983-03
5 schema:datePublishedReg 1983-03-01
6 schema:description ConclusionsIt has been established using as examples the interaction of 4-ethyl-4-isopropyl-, 4-tert-butyl-, and 4-(γ-hydroxypropyl)-4-hydroxy-2,6-di-tert-butylcyclohexa-2,5-dienones (quinols) with acetic anhydride and with hydrogen chloride in methanol that replacement of a tertiary butyl group by the nucleophile occurs in the process of acid decomposition.Reaction of 4-methyl-4-hydroxy-2,6-di-tert-butylcyclohexane-2,5-dienone with acetic anhydride and with hydrogen chloride in methanol occurs in a specific manner due to the formation of activated 2,6-di-tert-butylmethylenequinone in the reaction process.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N4435f5f0717c4cb4a4b81931c98b95d3
11 Nc1c6d40fcedf44429caa0398850f5b82
12 sg:journal.1022309
13 schema:keywords ConclusionsIt
14 acetic anhydride
15 acid decomposition
16 acid medium
17 anhydride
18 butyl groups
19 butylcyclohexa
20 butylcyclohexane
21 chloride
22 conversion
23 decomposition
24 di-tert
25 dienone
26 example
27 formation
28 group
29 hydrogen chloride
30 hydroxy
31 interaction
32 manner
33 medium
34 methanol
35 nucleophiles
36 process
37 reaction
38 reaction process
39 replacement
40 specific manner
41 tertiary butyl group
42 schema:name Dienone-phenol conversions of 4-x-substituted 4-hydroxy-2,6-di-tert-butylcyclohexa-2,5-dienones in acid media
43 schema:pagination 550-552
44 schema:productId Nb471f4f9967743c9b7b0737ae43c3815
45 Nb9c54ed334784f30a00bdfc78ae63e41
46 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002367554
47 https://doi.org/10.1007/bf00953095
48 schema:sdDatePublished 2022-05-10T09:41
49 schema:sdLicense https://scigraph.springernature.com/explorer/license/
50 schema:sdPublisher N202e92dc401a4d55b6061cef7c1e1a05
51 schema:url https://doi.org/10.1007/bf00953095
52 sgo:license sg:explorer/license/
53 sgo:sdDataset articles
54 rdf:type schema:ScholarlyArticle
55 N0285fcd48cce4d00b394a392262b919c rdf:first sg:person.012407113573.82
56 rdf:rest rdf:nil
57 N16ed4754f70a493090ca96e03cf74e6a rdf:first sg:person.013375177735.01
58 rdf:rest N7cfe3a4b141a4864b8369581a92bd1ea
59 N202e92dc401a4d55b6061cef7c1e1a05 schema:name Springer Nature - SN SciGraph project
60 rdf:type schema:Organization
61 N4435f5f0717c4cb4a4b81931c98b95d3 schema:issueNumber 3
62 rdf:type schema:PublicationIssue
63 N7cfe3a4b141a4864b8369581a92bd1ea rdf:first sg:person.010414742241.10
64 rdf:rest N0285fcd48cce4d00b394a392262b919c
65 Nb471f4f9967743c9b7b0737ae43c3815 schema:name dimensions_id
66 schema:value pub.1002367554
67 rdf:type schema:PropertyValue
68 Nb9c54ed334784f30a00bdfc78ae63e41 schema:name doi
69 schema:value 10.1007/bf00953095
70 rdf:type schema:PropertyValue
71 Nc1c6d40fcedf44429caa0398850f5b82 schema:volumeNumber 32
72 rdf:type schema:PublicationVolume
73 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
74 schema:name Chemical Sciences
75 rdf:type schema:DefinedTerm
76 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
77 schema:name Physical Chemistry (incl. Structural)
78 rdf:type schema:DefinedTerm
79 sg:journal.1022309 schema:issn 1026-3500
80 1066-5285
81 schema:name Russian Chemical Bulletin
82 schema:publisher Springer Nature
83 rdf:type schema:Periodical
84 sg:person.010414742241.10 schema:affiliation grid-institutes:grid.424930.8
85 schema:familyName Ershov
86 schema:givenName V. V.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010414742241.10
88 rdf:type schema:Person
89 sg:person.012407113573.82 schema:affiliation grid-institutes:grid.424930.8
90 schema:familyName Volod'kin
91 schema:givenName A. A.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012407113573.82
93 rdf:type schema:Person
94 sg:person.013375177735.01 schema:affiliation grid-institutes:grid.424930.8
95 schema:familyName Malysheva
96 schema:givenName R. D.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013375177735.01
98 rdf:type schema:Person
99 grid-institutes:grid.424930.8 schema:alternateName Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow
100 schema:name Institute of Chemical Physics, Academy of Sciences of the USSR, Moscow
101 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...