Bromine- and iodine-containing (Haloalkyl)trichlorosilanes and methyl(Haloalkyl)chlorosilanes and their conversions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1978-10

AUTHORS

V. M. D'yakov, Yu. A. Lukina, M. G. Voronkov, L. I. Gubanova, G. A. Samsonova, S. N. Tandura

ABSTRACT

ConclusionsThe organosilicon monomers XCH2(CH3)33−nSiCln with X=Cl (n=2, 3) are smoothly converted when reacted with aluminum iodide or aluminum bromide into the corresponding C-iodo and C-bromo derivatives (X=I, Br). Compounds with the general formula X(CH2)m(CH3)3−n,SiCln with X=Cl are converted upon reaction with NaI into the corresponding C-iodo derivatives (X=I).When reacted with SbF3 or KHF2, (iodoalkyl)- and (bromoalkyl)trichlorosilanes are converted into the corresponding (haloalkyl)trifluorosilanes.The corresponding (iodoalkyl)- and (bromoalkyl)silatranes and their exo-D-methyl derivatives have been synthesized on the basis of the (haloalkyl)trichlorosilanes obtained. More... »

PAGES

2098-2104

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00946535

DOI

http://dx.doi.org/10.1007/bf00946535

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017397532


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