Decomposition of nitrogen-hydrogen complexes of decaborane(12). 1. The kinetics of the thermal decomposition of decaborane(12) diammoniate View Full Text


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Article Info

DATE

1978-02

AUTHORS

A. S. Rozenberg, G. N. Nechiporenko, A. P. Alekseev

ABSTRACT

ConclusionsDecaborane(12) diammoniate decomposes at a measurable rate at 180–225°C, hydrogen being eliminated. Decomposition occurs nonuniformly over the entire B10H12(NH3)2 crystal body.Two parallel reactions are involved in hydrogen elimination under the conditions of our experiments, one reversible and the other irreversible, the latter leading to the liberation of 2 moles of H2 through an autocatalytic first-order process. More... »

PAGES

284-287

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00923860

DOI

http://dx.doi.org/10.1007/bf00923860

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1013992734


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