Oxidation of transition metals in the liquid phase View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1974-09

AUTHORS

I. P. Lavrent'ev, L. G. Korableva, E. A. Lavrent'eva, M. I. Khidekel', V. I. Ponomarev, L. O. Atovmyan

ABSTRACT

The oxidation of iron with CCl4 was carried out under mild conditions.In the interaction of metallic iron with CCl4 in dipolar aprotonic solvents (acetonitrile, benzonitrile, dimethylformamide, dimethylsulfoxide), the following complexes were obtained: [Fe(AN)6][FeCl4]2, [Fe(BN)6][FeCl4]2, trans-[Fe(DMF)4Cl2][FeCl4], [Fe(DMF)3Cl2][FeCl4], cis- and trans-[Fe(DMSO)4Cl2]Cl and trans-[Fe(DMSO)4Cl2][FeCl4], the structure of which was established on the basis of the IR, NGR, and electronic spectra.The complex cis-[Fe(DMSO)4Cl2]2[FeCl4], containing Fe(II) and Fe(III),was synthesized, and its structure was determined. The oxidation of iron with CCl4 was carried out under mild conditions. In the interaction of metallic iron with CCl4 in dipolar aprotonic solvents (acetonitrile, benzonitrile, dimethylformamide, dimethylsulfoxide), the following complexes were obtained: [Fe(AN)6][FeCl4]2, [Fe(BN)6][FeCl4]2, trans-[Fe(DMF)4Cl2][FeCl4], [Fe(DMF)3Cl2][FeCl4], cis- and trans-[Fe(DMSO)4Cl2]Cl and trans-[Fe(DMSO)4Cl2][FeCl4], the structure of which was established on the basis of the IR, NGR, and electronic spectra. The complex cis-[Fe(DMSO)4Cl2]2[FeCl4], containing Fe(II) and Fe(III),was synthesized, and its structure was determined. More... »

PAGES

1885-1889

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00922781

DOI

http://dx.doi.org/10.1007/bf00922781

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019341782


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics", 
          "id": "https://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lavrent'ev", 
        "givenName": "I. P.", 
        "id": "sg:person.010763332055.72", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010763332055.72"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics", 
          "id": "https://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Korableva", 
        "givenName": "L. G.", 
        "id": "sg:person.011305276203.95", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011305276203.95"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics", 
          "id": "https://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lavrent'eva", 
        "givenName": "E. A.", 
        "id": "sg:person.011560712455.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011560712455.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics", 
          "id": "https://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Khidekel'", 
        "givenName": "M. I.", 
        "id": "sg:person.013647624231.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013647624231.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics", 
          "id": "https://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ponomarev", 
        "givenName": "V. I.", 
        "id": "sg:person.010535710631.46", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010535710631.46"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics", 
          "id": "https://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Atovmyan", 
        "givenName": "L. O.", 
        "id": "sg:person.013606277777.39", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013606277777.39"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0010-8545(00)80028-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003083426"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/jr9640002408", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005171768"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/bcsj.42.2778", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030812015"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0365110x6700324x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041378254"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50060a023", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055569796"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50074a050", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055570680"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100839a046", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055681418"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrev.183.383", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060442071"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrev.183.383", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060442071"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1974-09", 
    "datePublishedReg": "1974-09-01", 
    "description": "The oxidation of iron with CCl4 was carried out under mild conditions.In the interaction of metallic iron with CCl4 in dipolar aprotonic solvents (acetonitrile, benzonitrile, dimethylformamide, dimethylsulfoxide), the following complexes were obtained: [Fe(AN)6][FeCl4]2, [Fe(BN)6][FeCl4]2, trans-[Fe(DMF)4Cl2][FeCl4], [Fe(DMF)3Cl2][FeCl4], cis- and trans-[Fe(DMSO)4Cl2]Cl and trans-[Fe(DMSO)4Cl2][FeCl4], the structure of which was established on the basis of the IR, NGR, and electronic spectra.The complex cis-[Fe(DMSO)4Cl2]2[FeCl4], containing Fe(II) and Fe(III),was synthesized, and its structure was determined. The oxidation of iron with CCl4 was carried out under mild conditions. In the interaction of metallic iron with CCl4 in dipolar aprotonic solvents (acetonitrile, benzonitrile, dimethylformamide, dimethylsulfoxide), the following complexes were obtained: [Fe(AN)6][FeCl4]2, [Fe(BN)6][FeCl4]2, trans-[Fe(DMF)4Cl2][FeCl4], [Fe(DMF)3Cl2][FeCl4], cis- and trans-[Fe(DMSO)4Cl2]Cl and trans-[Fe(DMSO)4Cl2][FeCl4], the structure of which was established on the basis of the IR, NGR, and electronic spectra. The complex cis-[Fe(DMSO)4Cl2]2[FeCl4], containing Fe(II) and Fe(III),was synthesized, and its structure was determined.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00922781", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "9", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "23"
      }
    ], 
    "name": "Oxidation of transition metals in the liquid phase", 
    "pagination": "1885-1889", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "5c27fb76be28c844c2608c820601cd63dbe1d0505687cb1e81d1b27bdfa926fe"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00922781"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1019341782"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00922781", 
      "https://app.dimensions.ai/details/publication/pub.1019341782"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T01:11", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8697_00000531.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF00922781"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00922781'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00922781'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00922781'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00922781'


 

This table displays all metadata directly associated to this object as RDF triples.

120 TRIPLES      21 PREDICATES      35 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00922781 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N30145692f37c4539bc1d7185992cc98e
4 schema:citation https://doi.org/10.1016/s0010-8545(00)80028-4
5 https://doi.org/10.1021/ic50060a023
6 https://doi.org/10.1021/ic50074a050
7 https://doi.org/10.1021/j100839a046
8 https://doi.org/10.1039/jr9640002408
9 https://doi.org/10.1103/physrev.183.383
10 https://doi.org/10.1107/s0365110x6700324x
11 https://doi.org/10.1246/bcsj.42.2778
12 schema:datePublished 1974-09
13 schema:datePublishedReg 1974-09-01
14 schema:description The oxidation of iron with CCl4 was carried out under mild conditions.In the interaction of metallic iron with CCl4 in dipolar aprotonic solvents (acetonitrile, benzonitrile, dimethylformamide, dimethylsulfoxide), the following complexes were obtained: [Fe(AN)6][FeCl4]2, [Fe(BN)6][FeCl4]2, trans-[Fe(DMF)4Cl2][FeCl4], [Fe(DMF)3Cl2][FeCl4], cis- and trans-[Fe(DMSO)4Cl2]Cl and trans-[Fe(DMSO)4Cl2][FeCl4], the structure of which was established on the basis of the IR, NGR, and electronic spectra.The complex cis-[Fe(DMSO)4Cl2]2[FeCl4], containing Fe(II) and Fe(III),was synthesized, and its structure was determined. The oxidation of iron with CCl4 was carried out under mild conditions. In the interaction of metallic iron with CCl4 in dipolar aprotonic solvents (acetonitrile, benzonitrile, dimethylformamide, dimethylsulfoxide), the following complexes were obtained: [Fe(AN)6][FeCl4]2, [Fe(BN)6][FeCl4]2, trans-[Fe(DMF)4Cl2][FeCl4], [Fe(DMF)3Cl2][FeCl4], cis- and trans-[Fe(DMSO)4Cl2]Cl and trans-[Fe(DMSO)4Cl2][FeCl4], the structure of which was established on the basis of the IR, NGR, and electronic spectra. The complex cis-[Fe(DMSO)4Cl2]2[FeCl4], containing Fe(II) and Fe(III),was synthesized, and its structure was determined.
15 schema:genre research_article
16 schema:inLanguage en
17 schema:isAccessibleForFree false
18 schema:isPartOf N9ec4cb0272fc4c1a88faef4a8717c262
19 Ne50a1dadae6e45978293512185e46457
20 sg:journal.1022309
21 schema:name Oxidation of transition metals in the liquid phase
22 schema:pagination 1885-1889
23 schema:productId N08b5d601661d4f479de7b564436b07c4
24 N4dd09df73d6e4b36990142a3865f81d4
25 Nfda913ea8c6944b481f0b33a5df4c67a
26 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019341782
27 https://doi.org/10.1007/bf00922781
28 schema:sdDatePublished 2019-04-11T01:11
29 schema:sdLicense https://scigraph.springernature.com/explorer/license/
30 schema:sdPublisher N1e1dd549042345e3ba259990c83d8115
31 schema:url http://link.springer.com/10.1007%2FBF00922781
32 sgo:license sg:explorer/license/
33 sgo:sdDataset articles
34 rdf:type schema:ScholarlyArticle
35 N08b5d601661d4f479de7b564436b07c4 schema:name dimensions_id
36 schema:value pub.1019341782
37 rdf:type schema:PropertyValue
38 N1db4c92640444606a785bf949b3b0789 rdf:first sg:person.011305276203.95
39 rdf:rest N324ede5bc7204b4293047d7b2a4a5fab
40 N1e1dd549042345e3ba259990c83d8115 schema:name Springer Nature - SN SciGraph project
41 rdf:type schema:Organization
42 N30145692f37c4539bc1d7185992cc98e rdf:first sg:person.010763332055.72
43 rdf:rest N1db4c92640444606a785bf949b3b0789
44 N324ede5bc7204b4293047d7b2a4a5fab rdf:first sg:person.011560712455.37
45 rdf:rest Neb07415a838b471da88b8fc900ce60e3
46 N4dd09df73d6e4b36990142a3865f81d4 schema:name readcube_id
47 schema:value 5c27fb76be28c844c2608c820601cd63dbe1d0505687cb1e81d1b27bdfa926fe
48 rdf:type schema:PropertyValue
49 N6e0c0bbce87040a6a6a36800c1607a98 rdf:first sg:person.013606277777.39
50 rdf:rest rdf:nil
51 N9ec4cb0272fc4c1a88faef4a8717c262 schema:volumeNumber 23
52 rdf:type schema:PublicationVolume
53 Ncd3f2c44f4fe44e1b9e8a96c1cb6ef7d rdf:first sg:person.010535710631.46
54 rdf:rest N6e0c0bbce87040a6a6a36800c1607a98
55 Ne50a1dadae6e45978293512185e46457 schema:issueNumber 9
56 rdf:type schema:PublicationIssue
57 Neb07415a838b471da88b8fc900ce60e3 rdf:first sg:person.013647624231.70
58 rdf:rest Ncd3f2c44f4fe44e1b9e8a96c1cb6ef7d
59 Nfda913ea8c6944b481f0b33a5df4c67a schema:name doi
60 schema:value 10.1007/bf00922781
61 rdf:type schema:PropertyValue
62 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
63 schema:name Chemical Sciences
64 rdf:type schema:DefinedTerm
65 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
66 schema:name Inorganic Chemistry
67 rdf:type schema:DefinedTerm
68 sg:journal.1022309 schema:issn 1066-5285
69 1573-9171
70 schema:name Russian Chemical Bulletin
71 rdf:type schema:Periodical
72 sg:person.010535710631.46 schema:affiliation https://www.grid.ac/institutes/grid.418949.9
73 schema:familyName Ponomarev
74 schema:givenName V. I.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010535710631.46
76 rdf:type schema:Person
77 sg:person.010763332055.72 schema:affiliation https://www.grid.ac/institutes/grid.418949.9
78 schema:familyName Lavrent'ev
79 schema:givenName I. P.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010763332055.72
81 rdf:type schema:Person
82 sg:person.011305276203.95 schema:affiliation https://www.grid.ac/institutes/grid.418949.9
83 schema:familyName Korableva
84 schema:givenName L. G.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011305276203.95
86 rdf:type schema:Person
87 sg:person.011560712455.37 schema:affiliation https://www.grid.ac/institutes/grid.418949.9
88 schema:familyName Lavrent'eva
89 schema:givenName E. A.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011560712455.37
91 rdf:type schema:Person
92 sg:person.013606277777.39 schema:affiliation https://www.grid.ac/institutes/grid.418949.9
93 schema:familyName Atovmyan
94 schema:givenName L. O.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013606277777.39
96 rdf:type schema:Person
97 sg:person.013647624231.70 schema:affiliation https://www.grid.ac/institutes/grid.418949.9
98 schema:familyName Khidekel'
99 schema:givenName M. I.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013647624231.70
101 rdf:type schema:Person
102 https://doi.org/10.1016/s0010-8545(00)80028-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003083426
103 rdf:type schema:CreativeWork
104 https://doi.org/10.1021/ic50060a023 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055569796
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1021/ic50074a050 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055570680
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1021/j100839a046 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055681418
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1039/jr9640002408 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005171768
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1103/physrev.183.383 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060442071
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1107/s0365110x6700324x schema:sameAs https://app.dimensions.ai/details/publication/pub.1041378254
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1246/bcsj.42.2778 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030812015
117 rdf:type schema:CreativeWork
118 https://www.grid.ac/institutes/grid.418949.9 schema:alternateName Institute of Problems of Chemical Physics
119 schema:name Division of the Institute of Chemical Physics, Academy of Sciences of the USSR, Chernogolovka
120 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...