Heterochain polyamides Communication 9. Preparation of polyamides and polyamide-esters from 2,2′-alkylene (or arylene) bis-2-oxazolin-5-ones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1959-03

AUTHORS

T. M. Frunze, V. V. Korshak, L. V. Kozlov

ABSTRACT

Polyamides and polyamide-esters were synthesized by the reaction of bisoxazolinones with diamines, diols, and amino alcohols.Polyamides of regular structure formed by reaction of bisoxazolinones with diamines have higher melting points than polyamides with a random distribution of monomer residues, such as are obtained by direct polycondensation.In the case of the polymers of regular structure, replacement of the octamethylene group by the phenylene group leads to greater rise in melting point than in the case of the polymers having macromolecules of irregular structure. More... »

PAGES

507-510

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00917709

DOI

http://dx.doi.org/10.1007/bf00917709

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006502476


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR", 
          "id": "http://www.grid.ac/institutes/grid.465443.4", 
          "name": [
            "Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Frunze", 
        "givenName": "T. M.", 
        "id": "sg:person.012430016053.71", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012430016053.71"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR", 
          "id": "http://www.grid.ac/institutes/grid.465443.4", 
          "name": [
            "Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Korshak", 
        "givenName": "V. V.", 
        "id": "sg:person.07530254221.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07530254221.06"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR", 
          "id": "http://www.grid.ac/institutes/grid.465443.4", 
          "name": [
            "Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kozlov", 
        "givenName": "L. V.", 
        "id": "sg:person.016566461565.44", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016566461565.44"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "1959-03", 
    "datePublishedReg": "1959-03-01", 
    "description": "Polyamides and polyamide-esters were synthesized by the reaction of bisoxazolinones with diamines, diols, and amino alcohols.Polyamides of regular structure formed by reaction of bisoxazolinones with diamines have higher melting points than polyamides with a random distribution of monomer residues, such as are obtained by direct polycondensation.In the case of the polymers of regular structure, replacement of the octamethylene group by the phenylene group leads to greater rise in melting point than in the case of the polymers having macromolecules of irregular structure.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00917709", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1063-5211", 
          "1026-3500"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "8"
      }
    ], 
    "keywords": [
      "preparation of polyamides", 
      "direct polycondensation", 
      "phenylene groups", 
      "high melting point", 
      "monomer residues", 
      "amino alcohols", 
      "polyamides", 
      "regular structure", 
      "polymers", 
      "diamines", 
      "melting point", 
      "octamethylene group", 
      "reaction", 
      "polycondensation", 
      "structure", 
      "heterochains", 
      "diol", 
      "macromolecules", 
      "preparation", 
      "irregular structure", 
      "alcohol", 
      "random distribution", 
      "residues", 
      "group", 
      "distribution", 
      "replacement", 
      "point", 
      "rise", 
      "cases", 
      "greater rise", 
      "reaction of bisoxazolinones", 
      "bisoxazolinones", 
      "Communication 9", 
      "bis-2-oxazolin-5-ones"
    ], 
    "name": "Heterochain polyamides Communication 9. Preparation of polyamides and polyamide-esters from 2,2\u2032-alkylene (or arylene) bis-2-oxazolin-5-ones", 
    "pagination": "507-510", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1006502476"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00917709"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00917709", 
      "https://app.dimensions.ai/details/publication/pub.1006502476"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:21", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_62.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00917709"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00917709'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00917709'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00917709'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00917709'


 

This table displays all metadata directly associated to this object as RDF triples.

106 TRIPLES      21 PREDICATES      60 URIs      52 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00917709 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author N247f78104a7e4330b4beb16f4e904f4e
4 schema:datePublished 1959-03
5 schema:datePublishedReg 1959-03-01
6 schema:description Polyamides and polyamide-esters were synthesized by the reaction of bisoxazolinones with diamines, diols, and amino alcohols.Polyamides of regular structure formed by reaction of bisoxazolinones with diamines have higher melting points than polyamides with a random distribution of monomer residues, such as are obtained by direct polycondensation.In the case of the polymers of regular structure, replacement of the octamethylene group by the phenylene group leads to greater rise in melting point than in the case of the polymers having macromolecules of irregular structure.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N2e0fe853d50c442f980e6322dcb15013
11 N7e5207407c0047a0bf136a9beab255c3
12 sg:journal.1022309
13 schema:keywords Communication 9
14 alcohol
15 amino alcohols
16 bis-2-oxazolin-5-ones
17 bisoxazolinones
18 cases
19 diamines
20 diol
21 direct polycondensation
22 distribution
23 greater rise
24 group
25 heterochains
26 high melting point
27 irregular structure
28 macromolecules
29 melting point
30 monomer residues
31 octamethylene group
32 phenylene groups
33 point
34 polyamides
35 polycondensation
36 polymers
37 preparation
38 preparation of polyamides
39 random distribution
40 reaction
41 reaction of bisoxazolinones
42 regular structure
43 replacement
44 residues
45 rise
46 structure
47 schema:name Heterochain polyamides Communication 9. Preparation of polyamides and polyamide-esters from 2,2′-alkylene (or arylene) bis-2-oxazolin-5-ones
48 schema:pagination 507-510
49 schema:productId N8535d09a5a034a0489dba71db4cb6734
50 Nddcbaea223b6491094b699ef83d16869
51 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006502476
52 https://doi.org/10.1007/bf00917709
53 schema:sdDatePublished 2021-11-01T18:21
54 schema:sdLicense https://scigraph.springernature.com/explorer/license/
55 schema:sdPublisher N74ca72c7527e42aa9e1f4f470014d614
56 schema:url https://doi.org/10.1007/bf00917709
57 sgo:license sg:explorer/license/
58 sgo:sdDataset articles
59 rdf:type schema:ScholarlyArticle
60 N247f78104a7e4330b4beb16f4e904f4e rdf:first sg:person.012430016053.71
61 rdf:rest N4744a0b8f6cd4e62b5a90aaef5472434
62 N2e0fe853d50c442f980e6322dcb15013 schema:volumeNumber 8
63 rdf:type schema:PublicationVolume
64 N4744a0b8f6cd4e62b5a90aaef5472434 rdf:first sg:person.07530254221.06
65 rdf:rest N6d4e5408a5bd4a2ebdc2213b432c3b9c
66 N6d4e5408a5bd4a2ebdc2213b432c3b9c rdf:first sg:person.016566461565.44
67 rdf:rest rdf:nil
68 N74ca72c7527e42aa9e1f4f470014d614 schema:name Springer Nature - SN SciGraph project
69 rdf:type schema:Organization
70 N7e5207407c0047a0bf136a9beab255c3 schema:issueNumber 3
71 rdf:type schema:PublicationIssue
72 N8535d09a5a034a0489dba71db4cb6734 schema:name dimensions_id
73 schema:value pub.1006502476
74 rdf:type schema:PropertyValue
75 Nddcbaea223b6491094b699ef83d16869 schema:name doi
76 schema:value 10.1007/bf00917709
77 rdf:type schema:PropertyValue
78 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
79 schema:name Chemical Sciences
80 rdf:type schema:DefinedTerm
81 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
82 schema:name Macromolecular and Materials Chemistry
83 rdf:type schema:DefinedTerm
84 sg:journal.1022309 schema:issn 1026-3500
85 1063-5211
86 schema:name Russian Chemical Bulletin
87 schema:publisher Springer Nature
88 rdf:type schema:Periodical
89 sg:person.012430016053.71 schema:affiliation grid-institutes:grid.465443.4
90 schema:familyName Frunze
91 schema:givenName T. M.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012430016053.71
93 rdf:type schema:Person
94 sg:person.016566461565.44 schema:affiliation grid-institutes:grid.465443.4
95 schema:familyName Kozlov
96 schema:givenName L. V.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016566461565.44
98 rdf:type schema:Person
99 sg:person.07530254221.06 schema:affiliation grid-institutes:grid.465443.4
100 schema:familyName Korshak
101 schema:givenName V. V.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07530254221.06
103 rdf:type schema:Person
104 grid-institutes:grid.465443.4 schema:alternateName Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR
105 schema:name Institute of Heteroorganic Compounds of the Academy of Sciences of the USSR, USSR
106 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...