Ontology type: schema:ScholarlyArticle
1969-10
AUTHORSL. Kh. Freidlin, N. V. Borunova, S. S. Daniélova, A. S. Nekrasov, L. I. Gvinter
ABSTRACTConclusionsIn the presence of a Co catalyst at temperatures up to 120° and pressures up to 80 atm, aceto-and propiophenone are reduced only at the carbonyl group; there are no products of hydrogenation of the aromatic ring in the catalyzate.The alkylphenylcarbinol formed undergoes hydrogenolysis at the C-OH bond on a Co catalyst even at room temperature. At 100° and 80 atm, an aliphatic-aromatic ketone is entirely reduced to the hydrocarbon.In the presence of an Ni-Al2O3 catalyst, reduction of the C=O group of the ketone and hydrogenolysis of the C-OH bond of the alkylphenylcarbinol predominate, but the aromatic ring is also partially hydrogenated.Hydrogenation and hydrogenolysis proceed on different portions of the active surface: selective reduction of the ketone to an alkylphenylcarbinol can be achieved by partial poisoning of a Co or Ni catalyst with cadmium (or lead). More... »
PAGES2137-2140
http://scigraph.springernature.com/pub.10.1007/bf00906635
DOIhttp://dx.doi.org/10.1007/bf00906635
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1036375021
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciencs of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.464621.3",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciencs of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Freidlin",
"givenName": "L. Kh.",
"id": "sg:person.011713374701.13",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011713374701.13"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciencs of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.464621.3",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciencs of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Borunova",
"givenName": "N. V.",
"id": "sg:person.07370266201.21",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07370266201.21"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciencs of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.464621.3",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciencs of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Dani\u00e9lova",
"givenName": "S. S.",
"id": "sg:person.016460732125.00",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016460732125.00"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciencs of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.464621.3",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciencs of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Nekrasov",
"givenName": "A. S.",
"id": "sg:person.014505324241.37",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014505324241.37"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciencs of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.464621.3",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciencs of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Gvinter",
"givenName": "L. I.",
"id": "sg:person.013423307113.48",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013423307113.48"
],
"type": "Person"
}
],
"datePublished": "1969-10",
"datePublishedReg": "1969-10-01",
"description": "ConclusionsIn the presence of a Co catalyst at temperatures up to 120\u00b0 and pressures up to 80 atm, aceto-and propiophenone are reduced only at the carbonyl group; there are no products of hydrogenation of the aromatic ring in the catalyzate.The alkylphenylcarbinol formed undergoes hydrogenolysis at the C-OH bond on a Co catalyst even at room temperature. At 100\u00b0 and 80 atm, an aliphatic-aromatic ketone is entirely reduced to the hydrocarbon.In the presence of an Ni-Al2O3 catalyst, reduction of the C=O group of the ketone and hydrogenolysis of the C-OH bond of the alkylphenylcarbinol predominate, but the aromatic ring is also partially hydrogenated.Hydrogenation and hydrogenolysis proceed on different portions of the active surface: selective reduction of the ketone to an alkylphenylcarbinol can be achieved by partial poisoning of a Co or Ni catalyst with cadmium (or lead).",
"genre": "article",
"id": "sg:pub.10.1007/bf00906635",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1022309",
"issn": [
"1026-3500",
"1066-5285"
],
"name": "Russian Chemical Bulletin",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "10",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "18"
}
],
"keywords": [
"Co catalysts",
"OH bond",
"aromatic ring",
"Ni\u2013Al2O3 catalyst",
"presence of CO",
"products of hydrogenation",
"Ni catalyst",
"carbonyl group",
"partial poisoning",
"catalyst",
"active surface",
"hydrogenolysis",
"selective reduction",
"ketones",
"hydrogenation",
"bonds",
"room temperature",
"propiophenone",
"influence of poisons",
"CO",
"ring",
"temperature",
"hydrocarbons",
"catalyzate",
"Ni",
"presence",
"aceto",
"atm",
"surface",
"cadmium",
"reduction",
"products",
"poisons",
"pressure",
"influence",
"poisoning",
"investigation",
"different portions",
"group",
"predominate",
"portion",
"ConclusionsIn"
],
"name": "Investigation of the reduction of aceto- and propiophenone in the presence of Co and Ni catalysts: Influence of poisons",
"pagination": "2137-2140",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1036375021"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf00906635"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf00906635",
"https://app.dimensions.ai/details/publication/pub.1036375021"
],
"sdDataset": "articles",
"sdDatePublished": "2022-06-01T22:23",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220601/entities/gbq_results/article/article_96.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/bf00906635"
}
]
Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00906635'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00906635'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00906635'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00906635'
This table displays all metadata directly associated to this object as RDF triples.
128 TRIPLES
21 PREDICATES
68 URIs
60 LITERALS
6 BLANK NODES