Destruction of polyacetals in acid media View Full Text


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Article Info

DATE

1970-10

AUTHORS

L. V. Ivanova, Yu. V. Moiseev, G. E. Zaikov, V. V. Ivanov

ABSTRACT

ConclusionsThe kinetics of the hydrolysis of methylal in aqueous solutions of sulfuric acid was investigated by the method of gas-liquid chromatography.A linear dependence of the logarithm of the effective rate constant of the reaction, calculated according to first order, on the Hammett acidity function H0 was demonstrated.The kinetic isotopic effect in solutions of 10% and 20% H2SO4 at 25° is equal to three.The hydrolysis of methylal proceeds according to an A-1 mechanism. More... »

PAGES

2104-2106

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00861477

DOI

http://dx.doi.org/10.1007/bf00861477

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1007714491


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