Study of the direction of hydrogen addition to dienones in the presence of pentacyanocobaltate View Full Text


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Article Info

DATE

1972-10

AUTHORS

L. I. Gvinter, L. Kh. Freidlin, N. V. Borunova, G. Ya. Starodubskaya

ABSTRACT

ConclusionsPentacyanocobaltate catalyzes the hydrogenation of 6-methyl-3, 5-heptadien-2-one (and of 3, 5-heptadien-2-one) at the 5, 6 double bond, and also the 1,4-addition of hydrogen to the diene system of the dienone. The C=C bond in the 3, 4 position hardly reacts.The cobalt complex accelerates the saturation of the activated C=C bond of 6-methyl-3-hepten-2-one. The isolated ethylene bond of 6-methyl-5-hepten-2-one fails to hydrogenate. More... »

PAGES

2248-2250

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00855309

DOI

http://dx.doi.org/10.1007/bf00855309

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032914688


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