Change in the selectivity of the action of catalysts in the hydrogenation of the dienone group View Full Text


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Article Info

DATE

1973-03

AUTHORS

N. V. Borunova, T. Ya. Rubinskaya, T. Atabekov, L. Kh. Freidlin, V. A. Zamureenko

ABSTRACT

ConclusionsIn the case of the modification of Ni-black with the lead cation, as well as that of Ni-catalysts on carriers, the direction of the addition of H2 to a dienone is changed; the basic product of hydrogenation is 5-hepten-2-one.It was established by the method of deuteroexchange that on Ni-black modified with firmly adsorbed Pb, saturation of the 3,4-double bond occurs not only by the direct addition of H2 to the C=C bond, but also by 1,4-addition to the C=C-C=0 group of the dienone. More... »

PAGES

495-497

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00854010

DOI

http://dx.doi.org/10.1007/bf00854010

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041079212


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