Ontology type: schema:ScholarlyArticle
1973-03
AUTHORSN. V. Borunova, T. Ya. Rubinskaya, T. Atabekov, L. Kh. Freidlin, V. A. Zamureenko
ABSTRACTConclusionsIn the case of the modification of Ni-black with the lead cation, as well as that of Ni-catalysts on carriers, the direction of the addition of H2 to a dienone is changed; the basic product of hydrogenation is 5-hepten-2-one.It was established by the method of deuteroexchange that on Ni-black modified with firmly adsorbed Pb, saturation of the 3,4-double bond occurs not only by the direct addition of H2 to the C=C bond, but also by 1,4-addition to the C=C-C=0 group of the dienone. More... »
PAGES495-497
http://scigraph.springernature.com/pub.10.1007/bf00854010
DOIhttp://dx.doi.org/10.1007/bf00854010
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1041079212
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.439283.7",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Borunova",
"givenName": "N. V.",
"id": "sg:person.07370266201.21",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07370266201.21"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.439283.7",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Rubinskaya",
"givenName": "T. Ya.",
"id": "sg:person.013651253037.56",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013651253037.56"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.439283.7",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Atabekov",
"givenName": "T.",
"id": "sg:person.010344326545.76",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010344326545.76"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.439283.7",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Freidlin",
"givenName": "L. Kh.",
"id": "sg:person.011713374701.13",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011713374701.13"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.439283.7",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Zamureenko",
"givenName": "V. A.",
"id": "sg:person.012070454153.29",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012070454153.29"
],
"type": "Person"
}
],
"datePublished": "1973-03",
"datePublishedReg": "1973-03-01",
"description": "ConclusionsIn the case of the modification of Ni-black with the lead cation, as well as that of Ni-catalysts on carriers, the direction of the addition of H2 to a dienone is changed; the basic product of hydrogenation is 5-hepten-2-one.It was established by the method of deuteroexchange that on Ni-black modified with firmly adsorbed Pb, saturation of the 3,4-double bond occurs not only by the direct addition of H2 to the C=C bond, but also by 1,4-addition to the C=C-C=0 group of the dienone.",
"genre": "article",
"id": "sg:pub.10.1007/bf00854010",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1022309",
"issn": [
"1026-3500",
"1066-5285"
],
"name": "Russian Chemical Bulletin",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "3",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "22"
}
],
"keywords": [
"modification of Ni",
"action of catalysts",
"Ni catalyst",
"lead cations",
"addition of H2",
"dienone group",
"double bond",
"direct addition",
"hydrogenation",
"bonds",
"dienone",
"H2",
"catalyst",
"cations",
"basic products",
"selectivity",
"deuteroexchange",
"Ni",
"products",
"carriers",
"modification",
"addition",
"Pb",
"group",
"method",
"saturation",
"changes",
"action",
"direction",
"cases",
"ConclusionsIn"
],
"name": "Change in the selectivity of the action of catalysts in the hydrogenation of the dienone group",
"pagination": "495-497",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1041079212"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf00854010"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf00854010",
"https://app.dimensions.ai/details/publication/pub.1041079212"
],
"sdDataset": "articles",
"sdDatePublished": "2022-05-20T07:17",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_141.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/bf00854010"
}
]
Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00854010'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00854010'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00854010'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00854010'
This table displays all metadata directly associated to this object as RDF triples.
117 TRIPLES
21 PREDICATES
57 URIs
49 LITERALS
6 BLANK NODES