Ontology type: schema:ScholarlyArticle
1972-05
AUTHORSN. V. Borunova, A. A. Slinkin, L. Kh. Freidlin, T. Atabekov
ABSTRACTConclusionsThe modifying action of cadmium (and zinc) cations on a Ni-Al2O3 catalyst with respect to the direction of addition of hydrogen to crotonylidenacetone is similar to the action of metallic cadmium.The modifying action of cadmium and zinc ions is specific. In contrast to these cations, treatment of a nickel catalyst with silver acetate has no influence on the direction of the addition of hydrogen to the dienone.Under conditions of hydrogenation in the presence of a Ni-Al2O3 catalyst, the cadmium cation is not reduced to the metal. More... »
PAGES1012-1015
http://scigraph.springernature.com/pub.10.1007/bf00853758
DOIhttp://dx.doi.org/10.1007/bf00853758
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1050303301
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Inorganic Chemistry",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.439283.7",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Borunova",
"givenName": "N. V.",
"id": "sg:person.07370266201.21",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07370266201.21"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.439283.7",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Slinkin",
"givenName": "A. A.",
"id": "sg:person.015752731107.94",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015752731107.94"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.439283.7",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Freidlin",
"givenName": "L. Kh.",
"id": "sg:person.011713374701.13",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011713374701.13"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR",
"id": "http://www.grid.ac/institutes/grid.439283.7",
"name": [
"N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR"
],
"type": "Organization"
},
"familyName": "Atabekov",
"givenName": "T.",
"id": "sg:person.010344326545.76",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010344326545.76"
],
"type": "Person"
}
],
"datePublished": "1972-05",
"datePublishedReg": "1972-05-01",
"description": "ConclusionsThe modifying action of cadmium (and zinc) cations on a Ni-Al2O3 catalyst with respect to the direction of addition of hydrogen to crotonylidenacetone is similar to the action of metallic cadmium.The modifying action of cadmium and zinc ions is specific. In contrast to these cations, treatment of a nickel catalyst with silver acetate has no influence on the direction of the addition of hydrogen to the dienone.Under conditions of hydrogenation in the presence of a Ni-Al2O3 catalyst, the cadmium cation is not reduced to the metal.",
"genre": "article",
"id": "sg:pub.10.1007/bf00853758",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1022309",
"issn": [
"1026-3500",
"1066-5285"
],
"name": "Russian Chemical Bulletin",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "5",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "21"
}
],
"keywords": [
"Ni\u2013Al2O3 catalyst",
"cadmium cations",
"action of catalysts",
"direction of addition",
"nickel catalysts",
"addition of hydrogen",
"dienone group",
"catalyst",
"silver acetate",
"conditions of hydrogenation",
"cations",
"zinc ions",
"metallic cadmium",
"hydrogenation",
"hydrogen",
"cadmium",
"selectivity",
"dienone",
"ions",
"action of cadmium",
"metals",
"acetate",
"addition",
"presence",
"conditions",
"influence",
"group",
"respect",
"action",
"contrast",
"changes",
"direction",
"treatment"
],
"name": "Change in the selectivity of the action of catalysts during the hydrogenation of the dienone group",
"pagination": "1012-1015",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1050303301"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf00853758"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf00853758",
"https://app.dimensions.ai/details/publication/pub.1050303301"
],
"sdDataset": "articles",
"sdDatePublished": "2022-06-01T21:57",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220601/entities/gbq_results/article/article_129.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/bf00853758"
}
]
Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00853758'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00853758'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00853758'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00853758'
This table displays all metadata directly associated to this object as RDF triples.
116 TRIPLES
21 PREDICATES
60 URIs
51 LITERALS
6 BLANK NODES