Influence of dry operating conditions: observation of oscillations and low temperature CO oxidation over Co3O4 and Au/Co3O4 catalysts View Full Text


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Article Info

DATE

1994-09

AUTHORS

D. A. H. Cunningham, T. Kobayashi, N. Kamijo, M. Haruta

ABSTRACT

The effect of dry operating conditions upon the oxidation of CO over Co3O4 and Au/Co3O4 has been studied. Under dry conditions (with pretreatment and reaction gases dried at −76°C using molecular sieve traps) oxidation of CO over Co3O4 can be observed at temperatures as low as −54°C. However, without sufficient drying Co3O4 rapidly deactivates. On the other hand, the Au/Co3O4 catalyst is resistant to the presence of moisture even at low temperatures. For both the Co3O4 and Au/Co3O4 catalytic systems, strong and periodic oscillations in percentage conversion and catalyst bed temperature have been observed. More... »

PAGES

257-264

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00816305

DOI

http://dx.doi.org/10.1007/bf00816305

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012801865


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