Preparation of supported gold catalysts from gold complexes and their catalytic activities for CO oxidation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1996-03

AUTHORS

Youzhu Yuan, Kiyotaka Asakura, Huilin Wan, Khirui Tsai, Yasuhiro Iwasawa

ABSTRACT

A phosphine-stabilized mononuclear gold complex Au(PPh3)(NO3) (1) and a phosphine-stabilized gold cluster [Aug(PPh3)8](NO3)3 (2) were used as precursors for preparation of supported gold catalysts. Both complexes 1 and 2 supported on inorganic oxides such as α-Fe2O3, TiO2, and SiO2 were inactive for CO oxidation, whereas the 1 or 2/ oxides treated under air or CO or 5% h2/Ar atmosphere were found to be active for CO oxidation. The catalytic activity depended on not only the treatment conditions but also the kinds of the precursor and the supports used. The catalysts derived from 1 showed higher activity than those derived from 2. α-Fe2O3 and TiO2 were much more efficient supports than SiO2 for the gold particles which were characterized by XRD and EXAFS. More... »

PAGES

15-20

References to SciGraph publications

  • 1983-12. Catalytic gold in GOLD BULLETIN
  • 1993-09. Low temperature CO oxidation over Au/TiO2 and Au/SiO2 catalysts in CATALYSIS LETTERS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/bf00814461

    DOI

    http://dx.doi.org/10.1007/bf00814461

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1006891377


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Physical Chemistry (incl. Structural)", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Xiamen University", 
              "id": "https://www.grid.ac/institutes/grid.12955.3a", 
              "name": [
                "Department of Chemistry, Graduate School of Science, The University of Tokyo, Hongo, Bunkyo-ku, 113, Tokyo, Japan", 
                "Department of Chemistry and State Key Laboratory for Physical Chemistry of the Solid Surface, Xiamen University, 361005, Xiamen, PR China"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Yuan", 
            "givenName": "Youzhu", 
            "id": "sg:person.01250474777.15", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01250474777.15"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "University of Tokyo", 
              "id": "https://www.grid.ac/institutes/grid.26999.3d", 
              "name": [
                "Research Center for Spectrochemistry, Faculty of Science, The University of Tokyo, Hongo, Bunkyo-ku, 113, Tokyo, Japan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Asakura", 
            "givenName": "Kiyotaka", 
            "id": "sg:person.012555256351.52", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012555256351.52"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Xiamen University", 
              "id": "https://www.grid.ac/institutes/grid.12955.3a", 
              "name": [
                "Department of Chemistry and State Key Laboratory for Physical Chemistry of the Solid Surface, Xiamen University, 361005, Xiamen, PR China"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Wan", 
            "givenName": "Huilin", 
            "id": "sg:person.015537777013.40", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015537777013.40"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Xiamen University", 
              "id": "https://www.grid.ac/institutes/grid.12955.3a", 
              "name": [
                "Department of Chemistry and State Key Laboratory for Physical Chemistry of the Solid Surface, Xiamen University, 361005, Xiamen, PR China"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Tsai", 
            "givenName": "Khirui", 
            "id": "sg:person.01266773767.17", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01266773767.17"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "University of Tokyo", 
              "id": "https://www.grid.ac/institutes/grid.26999.3d", 
              "name": [
                "Department of Chemistry, Graduate School of Science, The University of Tokyo, Hongo, Bunkyo-ku, 113, Tokyo, Japan"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Iwasawa", 
            "givenName": "Yasuhiro", 
            "id": "sg:person.010046407535.09", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010046407535.09"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.1002/bbpc.19790830905", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1015190919"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0021-9517(91)90319-y", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1025010635"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1006/jcat.1993.1322", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1030655116"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0021-9517(75)90188-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1030869124"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0021-9517(70)90178-8", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031202936"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1080/01614949308014607", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031527766"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf00766147", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034271767", 
              "https://doi.org/10.1007/bf00766147"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf00766147", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1034271767", 
              "https://doi.org/10.1007/bf00766147"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf03214632", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1037749060", 
              "https://doi.org/10.1007/bf03214632"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1006/jcat.1995.1043", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1040902261"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0304-5102(93)e0163-b", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1042148413"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1016/0021-9517(89)90034-1", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1044585718"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/cr00035a003", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1053954616"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "1996-03", 
        "datePublishedReg": "1996-03-01", 
        "description": "A phosphine-stabilized mononuclear gold complex Au(PPh3)(NO3) (1) and a phosphine-stabilized gold cluster [Aug(PPh3)8](NO3)3 (2) were used as precursors for preparation of supported gold catalysts. Both complexes 1 and 2 supported on inorganic oxides such as \u03b1-Fe2O3, TiO2, and SiO2 were inactive for CO oxidation, whereas the 1 or 2/ oxides treated under air or CO or 5% h2/Ar atmosphere were found to be active for CO oxidation. The catalytic activity depended on not only the treatment conditions but also the kinds of the precursor and the supports used. The catalysts derived from 1 showed higher activity than those derived from 2. \u03b1-Fe2O3 and TiO2 were much more efficient supports than SiO2 for the gold particles which were characterized by XRD and EXAFS.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1007/bf00814461", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1126974", 
            "issn": [
              "1011-372X", 
              "1572-879X"
            ], 
            "name": "Catalysis Letters", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "1-2", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "42"
          }
        ], 
        "name": "Preparation of supported gold catalysts from gold complexes and their catalytic activities for CO oxidation", 
        "pagination": "15-20", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "20d3a3a71e6db072f54bd225302bd72ac9613eecb7c974a3af7a8ef80415ed72"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/bf00814461"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1006891377"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/bf00814461", 
          "https://app.dimensions.ai/details/publication/pub.1006891377"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T21:31", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8687_00000486.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1007/BF00814461"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00814461'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00814461'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00814461'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00814461'


     

    This table displays all metadata directly associated to this object as RDF triples.

    132 TRIPLES      21 PREDICATES      39 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/bf00814461 schema:about anzsrc-for:03
    2 anzsrc-for:0306
    3 schema:author N568aebb7a13b4b6cbe1a0e790f7edad1
    4 schema:citation sg:pub.10.1007/bf00766147
    5 sg:pub.10.1007/bf03214632
    6 https://doi.org/10.1002/bbpc.19790830905
    7 https://doi.org/10.1006/jcat.1993.1322
    8 https://doi.org/10.1006/jcat.1995.1043
    9 https://doi.org/10.1016/0021-9517(70)90178-8
    10 https://doi.org/10.1016/0021-9517(75)90188-8
    11 https://doi.org/10.1016/0021-9517(89)90034-1
    12 https://doi.org/10.1016/0021-9517(91)90319-y
    13 https://doi.org/10.1016/0304-5102(93)e0163-b
    14 https://doi.org/10.1021/cr00035a003
    15 https://doi.org/10.1080/01614949308014607
    16 schema:datePublished 1996-03
    17 schema:datePublishedReg 1996-03-01
    18 schema:description A phosphine-stabilized mononuclear gold complex Au(PPh3)(NO3) (1) and a phosphine-stabilized gold cluster [Aug(PPh3)8](NO3)3 (2) were used as precursors for preparation of supported gold catalysts. Both complexes 1 and 2 supported on inorganic oxides such as α-Fe2O3, TiO2, and SiO2 were inactive for CO oxidation, whereas the 1 or 2/ oxides treated under air or CO or 5% h2/Ar atmosphere were found to be active for CO oxidation. The catalytic activity depended on not only the treatment conditions but also the kinds of the precursor and the supports used. The catalysts derived from 1 showed higher activity than those derived from 2. α-Fe2O3 and TiO2 were much more efficient supports than SiO2 for the gold particles which were characterized by XRD and EXAFS.
    19 schema:genre research_article
    20 schema:inLanguage en
    21 schema:isAccessibleForFree false
    22 schema:isPartOf Nd89a0f2978fc42c9b3c776ef97734f4c
    23 Nfb81baf8183b481d9878847d815eda3b
    24 sg:journal.1126974
    25 schema:name Preparation of supported gold catalysts from gold complexes and their catalytic activities for CO oxidation
    26 schema:pagination 15-20
    27 schema:productId N7c651aba4d2a40a4969a16f9818d5100
    28 Nb0bcf0ae5b534ce5b0b652a6f0c69f32
    29 Neae78764d47e47d4851a7bbf09543120
    30 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006891377
    31 https://doi.org/10.1007/bf00814461
    32 schema:sdDatePublished 2019-04-10T21:31
    33 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    34 schema:sdPublisher N97175589f72f4c89943b719393425137
    35 schema:url http://link.springer.com/10.1007/BF00814461
    36 sgo:license sg:explorer/license/
    37 sgo:sdDataset articles
    38 rdf:type schema:ScholarlyArticle
    39 N2f1e543cf1f44f16b4e61fc5baa11f73 rdf:first sg:person.01266773767.17
    40 rdf:rest N4a4d8d02ab81479f85717302f277e0a7
    41 N4a4d8d02ab81479f85717302f277e0a7 rdf:first sg:person.010046407535.09
    42 rdf:rest rdf:nil
    43 N568aebb7a13b4b6cbe1a0e790f7edad1 rdf:first sg:person.01250474777.15
    44 rdf:rest Nf50abc69599b4f33b1af7f15887644ab
    45 N5f1c7c624bd04c1481c84849160c1dd9 rdf:first sg:person.015537777013.40
    46 rdf:rest N2f1e543cf1f44f16b4e61fc5baa11f73
    47 N7c651aba4d2a40a4969a16f9818d5100 schema:name readcube_id
    48 schema:value 20d3a3a71e6db072f54bd225302bd72ac9613eecb7c974a3af7a8ef80415ed72
    49 rdf:type schema:PropertyValue
    50 N97175589f72f4c89943b719393425137 schema:name Springer Nature - SN SciGraph project
    51 rdf:type schema:Organization
    52 Nb0bcf0ae5b534ce5b0b652a6f0c69f32 schema:name dimensions_id
    53 schema:value pub.1006891377
    54 rdf:type schema:PropertyValue
    55 Nd89a0f2978fc42c9b3c776ef97734f4c schema:issueNumber 1-2
    56 rdf:type schema:PublicationIssue
    57 Neae78764d47e47d4851a7bbf09543120 schema:name doi
    58 schema:value 10.1007/bf00814461
    59 rdf:type schema:PropertyValue
    60 Nf50abc69599b4f33b1af7f15887644ab rdf:first sg:person.012555256351.52
    61 rdf:rest N5f1c7c624bd04c1481c84849160c1dd9
    62 Nfb81baf8183b481d9878847d815eda3b schema:volumeNumber 42
    63 rdf:type schema:PublicationVolume
    64 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    65 schema:name Chemical Sciences
    66 rdf:type schema:DefinedTerm
    67 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
    68 schema:name Physical Chemistry (incl. Structural)
    69 rdf:type schema:DefinedTerm
    70 sg:journal.1126974 schema:issn 1011-372X
    71 1572-879X
    72 schema:name Catalysis Letters
    73 rdf:type schema:Periodical
    74 sg:person.010046407535.09 schema:affiliation https://www.grid.ac/institutes/grid.26999.3d
    75 schema:familyName Iwasawa
    76 schema:givenName Yasuhiro
    77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010046407535.09
    78 rdf:type schema:Person
    79 sg:person.01250474777.15 schema:affiliation https://www.grid.ac/institutes/grid.12955.3a
    80 schema:familyName Yuan
    81 schema:givenName Youzhu
    82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01250474777.15
    83 rdf:type schema:Person
    84 sg:person.012555256351.52 schema:affiliation https://www.grid.ac/institutes/grid.26999.3d
    85 schema:familyName Asakura
    86 schema:givenName Kiyotaka
    87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012555256351.52
    88 rdf:type schema:Person
    89 sg:person.01266773767.17 schema:affiliation https://www.grid.ac/institutes/grid.12955.3a
    90 schema:familyName Tsai
    91 schema:givenName Khirui
    92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01266773767.17
    93 rdf:type schema:Person
    94 sg:person.015537777013.40 schema:affiliation https://www.grid.ac/institutes/grid.12955.3a
    95 schema:familyName Wan
    96 schema:givenName Huilin
    97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015537777013.40
    98 rdf:type schema:Person
    99 sg:pub.10.1007/bf00766147 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034271767
    100 https://doi.org/10.1007/bf00766147
    101 rdf:type schema:CreativeWork
    102 sg:pub.10.1007/bf03214632 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037749060
    103 https://doi.org/10.1007/bf03214632
    104 rdf:type schema:CreativeWork
    105 https://doi.org/10.1002/bbpc.19790830905 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015190919
    106 rdf:type schema:CreativeWork
    107 https://doi.org/10.1006/jcat.1993.1322 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030655116
    108 rdf:type schema:CreativeWork
    109 https://doi.org/10.1006/jcat.1995.1043 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040902261
    110 rdf:type schema:CreativeWork
    111 https://doi.org/10.1016/0021-9517(70)90178-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031202936
    112 rdf:type schema:CreativeWork
    113 https://doi.org/10.1016/0021-9517(75)90188-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030869124
    114 rdf:type schema:CreativeWork
    115 https://doi.org/10.1016/0021-9517(89)90034-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044585718
    116 rdf:type schema:CreativeWork
    117 https://doi.org/10.1016/0021-9517(91)90319-y schema:sameAs https://app.dimensions.ai/details/publication/pub.1025010635
    118 rdf:type schema:CreativeWork
    119 https://doi.org/10.1016/0304-5102(93)e0163-b schema:sameAs https://app.dimensions.ai/details/publication/pub.1042148413
    120 rdf:type schema:CreativeWork
    121 https://doi.org/10.1021/cr00035a003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053954616
    122 rdf:type schema:CreativeWork
    123 https://doi.org/10.1080/01614949308014607 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031527766
    124 rdf:type schema:CreativeWork
    125 https://www.grid.ac/institutes/grid.12955.3a schema:alternateName Xiamen University
    126 schema:name Department of Chemistry and State Key Laboratory for Physical Chemistry of the Solid Surface, Xiamen University, 361005, Xiamen, PR China
    127 Department of Chemistry, Graduate School of Science, The University of Tokyo, Hongo, Bunkyo-ku, 113, Tokyo, Japan
    128 rdf:type schema:Organization
    129 https://www.grid.ac/institutes/grid.26999.3d schema:alternateName University of Tokyo
    130 schema:name Department of Chemistry, Graduate School of Science, The University of Tokyo, Hongo, Bunkyo-ku, 113, Tokyo, Japan
    131 Research Center for Spectrochemistry, Faculty of Science, The University of Tokyo, Hongo, Bunkyo-ku, 113, Tokyo, Japan
    132 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...