Sn-ZSM-12, a new, large pore MTW type tin-silicate molecular sieve: synthesis, characterization and catalytic properties in oxidation reactions View Full Text


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Article Info

DATE

1995-09

AUTHORS

N. K. Mal, A. Bhaumik, R. Kumar, A. V. Ramaswamy

ABSTRACT

A new large pore tin-silicate analogue of zeolite ZSM-12 (MTW topology) with Si/Sn molar ratio >70 has been synthesized hydrothermally using a new template, hexamethylene bis(benzyl dimethyl ammonium hydroxide). This material exhibits an expansion in unit cell volume (XRD), an IR band at 970 cm−1 and a charge transfer band at 205 nm in the UV-Vis region indicating the presence of Si-O-Sn units with Sn4+ centers in Td configuration. Sn-ZSM-12 catalyzes the oxidation of phenol,m-cresol andm-xylene using dilute H2O2 as an oxidizing agent. More... »

PAGES

387-394

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00814240

DOI

http://dx.doi.org/10.1007/bf00814240

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051355642


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