Asymmetric catalysis, part 91: Enantioselective monophenylation ofcis-1,2-cyclopentanediol with triphenylbismuth diacetate and chiral copper(II) complexes as catalysts View Full Text


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Article Info

DATE

1994-12

AUTHORS

H. Brunner, T. Chuard

ABSTRACT

The monophenylation ofcis-1,2-cyclopentanediol with triphenylbismuth diacetate in the presence of chiral Cu(II) complexes as catalysts gavecis-2-hydroxy-1-phenoxy-cyclopentane with enantiomeric excesses up to 38%. The optically active ligands used were triamine derivatives of 2,6-bis(aminomethyl)pyridine and diamine derivatives of 2-(aminomethyl)pyridine. Selectivity in the monophenylation occurred only in the presence of the latter as auxiliary ligands. More... »

PAGES

1293-1300

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00811078

DOI

http://dx.doi.org/10.1007/bf00811078

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1045191227


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