Hydrierung von Silicium-Halogen-Verbindungen mittels Trialkylstannylchlorid/Natriumhydrid View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1995-05

AUTHORS

E. Hengge, C. Grogger, F. Uhlig, G. Roewer, U. Herzog, U. Pätzold

ABSTRACT

Organotinchlorides of the general formula R3SnCl and R2SnCl2 (R=Me,n-Bu, Ph) can easily be converted into the corresponding hydrides R3SiH and R2SiH2 employing NaH in diethylene glycol dialkyl ethers. Using trialkyltinhydrides like Bu3SnH in combination with a catalyst (tertiary amines, N-heterocycles, phosphonium or ammonium salts), Si-Cl bonds in mono- and disilanes are hydrogenated. In the case of disilanes, Si-Si bond cleavage and concurrent hydrogenation can be afforded with strongly nucleophilic catalysts. Partial hydrogenation is also possible. The whole process can be run cyclically. More... »

PAGES

549-555

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00807428

DOI

http://dx.doi.org/10.1007/bf00807428

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1035591394


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