A novel microfabricated Pd/SiO2 model catalyst for the hydrogenation of 1,3-butadiene View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1994-03

AUTHORS

A. C. Krauth, K. H. Lee, G. H. Bernstein, E. E. Wolf

ABSTRACT

The hydrogenation of 1,3-butadiene was successfully demonstrated using a microfabricated catalyst. The reaction was carried out at atmospheric pressure and 100°C with a hydrogen to hydrocarbon ratio of 125. Data from a thin film Pd/silica catalyst is also presented for comparison. The conversion for the microfabricated catalyst is more stable and slightly lower than that for the thin film catalyst; however, the geometric surface area of the thin film catalyst is 7.5 times greater than that of the microfabricated catalyst. The selectivity of the reaction products is greatly different between the two catalysts. The microfabricated catalyst has a much lower selectivity for 1-butene and favors the 2-butenes more so than does the thin film catalyst. More... »

PAGES

43-51

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00806976

DOI

http://dx.doi.org/10.1007/bf00806976

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026573707


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Notre Dame", 
          "id": "https://www.grid.ac/institutes/grid.131063.6", 
          "name": [
            "Department of Chemical Engineering, University of Notre Dame, 46556, Notre Dame, IN, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Krauth", 
        "givenName": "A. C.", 
        "id": "sg:person.012542003561.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012542003561.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Notre Dame", 
          "id": "https://www.grid.ac/institutes/grid.131063.6", 
          "name": [
            "Department of Chemical Engineering, University of Notre Dame, 46556, Notre Dame, IN, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lee", 
        "givenName": "K. H.", 
        "id": "sg:person.015277636271.22", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015277636271.22"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Notre Dame", 
          "id": "https://www.grid.ac/institutes/grid.131063.6", 
          "name": [
            "Department of Electrical Engineering, University of Notre Dame, 46556, Notre Dame, IN, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bernstein", 
        "givenName": "G. H.", 
        "id": "sg:person.01002520764.50", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01002520764.50"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Notre Dame", 
          "id": "https://www.grid.ac/institutes/grid.131063.6", 
          "name": [
            "Department of Chemical Engineering, University of Notre Dame, 46556, Notre Dame, IN, USA"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wolf", 
        "givenName": "E. E.", 
        "id": "sg:person.010652202325.22", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010652202325.22"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/s0166-9834(00)80910-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009376270"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0166-9834(00)82293-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032263598"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1006/jcat.1993.1164", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037401844"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9517(91)90002-l", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038808754"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00773183", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052688945", 
          "https://doi.org/10.1007/bf00773183"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1126/science.258.5086.1337", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062544968"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1994-03", 
    "datePublishedReg": "1994-03-01", 
    "description": "The hydrogenation of 1,3-butadiene was successfully demonstrated using a microfabricated catalyst. The reaction was carried out at atmospheric pressure and 100\u00b0C with a hydrogen to hydrocarbon ratio of 125. Data from a thin film Pd/silica catalyst is also presented for comparison. The conversion for the microfabricated catalyst is more stable and slightly lower than that for the thin film catalyst; however, the geometric surface area of the thin film catalyst is 7.5 times greater than that of the microfabricated catalyst. The selectivity of the reaction products is greatly different between the two catalysts. The microfabricated catalyst has a much lower selectivity for 1-butene and favors the 2-butenes more so than does the thin film catalyst.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00806976", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1126974", 
        "issn": [
          "1011-372X", 
          "1572-879X"
        ], 
        "name": "Catalysis Letters", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1-2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "27"
      }
    ], 
    "name": "A novel microfabricated Pd/SiO2 model catalyst for the hydrogenation of 1,3-butadiene", 
    "pagination": "43-51", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "7e989e1fe5c58735884a233efebd9a82ca52dfc4f9abe24c787dcc0a98f70d2b"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00806976"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1026573707"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00806976", 
      "https://app.dimensions.ai/details/publication/pub.1026573707"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T20:39", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8684_00000481.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF00806976"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00806976'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00806976'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00806976'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00806976'


 

This table displays all metadata directly associated to this object as RDF triples.

102 TRIPLES      21 PREDICATES      33 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00806976 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nbe1e2ef285514b39be3b5fcb7718c220
4 schema:citation sg:pub.10.1007/bf00773183
5 https://doi.org/10.1006/jcat.1993.1164
6 https://doi.org/10.1016/0021-9517(91)90002-l
7 https://doi.org/10.1016/s0166-9834(00)80910-0
8 https://doi.org/10.1016/s0166-9834(00)82293-9
9 https://doi.org/10.1126/science.258.5086.1337
10 schema:datePublished 1994-03
11 schema:datePublishedReg 1994-03-01
12 schema:description The hydrogenation of 1,3-butadiene was successfully demonstrated using a microfabricated catalyst. The reaction was carried out at atmospheric pressure and 100°C with a hydrogen to hydrocarbon ratio of 125. Data from a thin film Pd/silica catalyst is also presented for comparison. The conversion for the microfabricated catalyst is more stable and slightly lower than that for the thin film catalyst; however, the geometric surface area of the thin film catalyst is 7.5 times greater than that of the microfabricated catalyst. The selectivity of the reaction products is greatly different between the two catalysts. The microfabricated catalyst has a much lower selectivity for 1-butene and favors the 2-butenes more so than does the thin film catalyst.
13 schema:genre research_article
14 schema:inLanguage en
15 schema:isAccessibleForFree false
16 schema:isPartOf N52fb1f4230c54bc8b9f089e9d58b14f0
17 N9bcb49efc66d4490b6b8a711b2e771bf
18 sg:journal.1126974
19 schema:name A novel microfabricated Pd/SiO2 model catalyst for the hydrogenation of 1,3-butadiene
20 schema:pagination 43-51
21 schema:productId N5b44df75fb9743a9a194f187cbd154a7
22 N5f00e573db0046ccb747e8e58c67a7b1
23 N87503c3cf2bd424bbf83974f7c9b9804
24 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026573707
25 https://doi.org/10.1007/bf00806976
26 schema:sdDatePublished 2019-04-10T20:39
27 schema:sdLicense https://scigraph.springernature.com/explorer/license/
28 schema:sdPublisher Nef2859bb58924ff5851def7c548fa411
29 schema:url http://link.springer.com/10.1007/BF00806976
30 sgo:license sg:explorer/license/
31 sgo:sdDataset articles
32 rdf:type schema:ScholarlyArticle
33 N36c78aedcf3e4d10a0ba5d6a6404c746 rdf:first sg:person.015277636271.22
34 rdf:rest N7ca2d35d1c734f57860472e5b6cf3c52
35 N46367cd45f2049eb854202c3121c42da rdf:first sg:person.010652202325.22
36 rdf:rest rdf:nil
37 N52fb1f4230c54bc8b9f089e9d58b14f0 schema:issueNumber 1-2
38 rdf:type schema:PublicationIssue
39 N5b44df75fb9743a9a194f187cbd154a7 schema:name readcube_id
40 schema:value 7e989e1fe5c58735884a233efebd9a82ca52dfc4f9abe24c787dcc0a98f70d2b
41 rdf:type schema:PropertyValue
42 N5f00e573db0046ccb747e8e58c67a7b1 schema:name doi
43 schema:value 10.1007/bf00806976
44 rdf:type schema:PropertyValue
45 N7ca2d35d1c734f57860472e5b6cf3c52 rdf:first sg:person.01002520764.50
46 rdf:rest N46367cd45f2049eb854202c3121c42da
47 N87503c3cf2bd424bbf83974f7c9b9804 schema:name dimensions_id
48 schema:value pub.1026573707
49 rdf:type schema:PropertyValue
50 N9bcb49efc66d4490b6b8a711b2e771bf schema:volumeNumber 27
51 rdf:type schema:PublicationVolume
52 Nbe1e2ef285514b39be3b5fcb7718c220 rdf:first sg:person.012542003561.75
53 rdf:rest N36c78aedcf3e4d10a0ba5d6a6404c746
54 Nef2859bb58924ff5851def7c548fa411 schema:name Springer Nature - SN SciGraph project
55 rdf:type schema:Organization
56 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
57 schema:name Chemical Sciences
58 rdf:type schema:DefinedTerm
59 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
60 schema:name Physical Chemistry (incl. Structural)
61 rdf:type schema:DefinedTerm
62 sg:journal.1126974 schema:issn 1011-372X
63 1572-879X
64 schema:name Catalysis Letters
65 rdf:type schema:Periodical
66 sg:person.01002520764.50 schema:affiliation https://www.grid.ac/institutes/grid.131063.6
67 schema:familyName Bernstein
68 schema:givenName G. H.
69 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01002520764.50
70 rdf:type schema:Person
71 sg:person.010652202325.22 schema:affiliation https://www.grid.ac/institutes/grid.131063.6
72 schema:familyName Wolf
73 schema:givenName E. E.
74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010652202325.22
75 rdf:type schema:Person
76 sg:person.012542003561.75 schema:affiliation https://www.grid.ac/institutes/grid.131063.6
77 schema:familyName Krauth
78 schema:givenName A. C.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012542003561.75
80 rdf:type schema:Person
81 sg:person.015277636271.22 schema:affiliation https://www.grid.ac/institutes/grid.131063.6
82 schema:familyName Lee
83 schema:givenName K. H.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015277636271.22
85 rdf:type schema:Person
86 sg:pub.10.1007/bf00773183 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052688945
87 https://doi.org/10.1007/bf00773183
88 rdf:type schema:CreativeWork
89 https://doi.org/10.1006/jcat.1993.1164 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037401844
90 rdf:type schema:CreativeWork
91 https://doi.org/10.1016/0021-9517(91)90002-l schema:sameAs https://app.dimensions.ai/details/publication/pub.1038808754
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1016/s0166-9834(00)80910-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009376270
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1016/s0166-9834(00)82293-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032263598
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1126/science.258.5086.1337 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062544968
98 rdf:type schema:CreativeWork
99 https://www.grid.ac/institutes/grid.131063.6 schema:alternateName University of Notre Dame
100 schema:name Department of Chemical Engineering, University of Notre Dame, 46556, Notre Dame, IN, USA
101 Department of Electrical Engineering, University of Notre Dame, 46556, Notre Dame, IN, USA
102 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...