Influence of the preparation method on the characteristics of TiO2-CeO2 supports View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1992-06

AUTHORS

A. Dauscher, P. Wehrer, L. Hilaire

ABSTRACT

The preparation by a sol-gel process of TiO2-CeO2 supports (Ce/Ti atomic ratio=1/1) was studied by varying the sol-gel processing conditions. Starting materials were Ti[OCH(CH3)2]4 and CeCl3-7H2O. The samples were characterised before and after calcination at 400 °C by BET, porosity measurements, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Working in acidic conditions leads to the formation of a compound that induces the growth of CeO2 on amorphous TiO2 during calcination. In a basic medium, a well defined CeTiO3 compound is obtained that allows the formation of a real mixed TiO2-CeO2 compound after calcination. It presents a specific area of 70 m2 g−1, a narrow distribution of mesopores and easily reducible cerium oxide. More... »

PAGES

171-183

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00765231

DOI

http://dx.doi.org/10.1007/bf00765231

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041579967


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "University of Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.11843.3f", 
          "name": [
            "Laboratoire d'Etude de la R\u00e9activit\u00e9 Catalytique, des Surfaces et Interfaces, URA 1498 du CNRS, Universit\u00e9 Louis Pasteur, 4 rue Blaise Pascal, 67070, Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dauscher", 
        "givenName": "A.", 
        "id": "sg:person.0716277067.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0716277067.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.11843.3f", 
          "name": [
            "Laboratoire d'Etude de la R\u00e9activit\u00e9 Catalytique, des Surfaces et Interfaces, URA 1498 du CNRS, Universit\u00e9 Louis Pasteur, 4 rue Blaise Pascal, 67070, Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wehrer", 
        "givenName": "P.", 
        "id": "sg:person.07516213064.88", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07516213064.88"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Strasbourg", 
          "id": "https://www.grid.ac/institutes/grid.11843.3f", 
          "name": [
            "Laboratoire d'Etude de la R\u00e9activit\u00e9 Catalytique, des Surfaces et Interfaces, URA 1498 du CNRS, Universit\u00e9 Louis Pasteur, 4 rue Blaise Pascal, 67070, Strasbourg Cedex, France"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hilaire", 
        "givenName": "L.", 
        "id": "sg:person.010654125447.03", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010654125447.03"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/zaac.19663430309", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000691382"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0166-9834(00)82873-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002003683"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9517(74)90201-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011564182"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0166-9834(00)80196-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017024823"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00765318", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019401871", 
          "https://doi.org/10.1007/bf00765318"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0038-1098(85)90223-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021004973"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0038-1098(85)90223-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021004973"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-3093(90)90149-g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021970344"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-3093(90)90149-g", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021970344"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-3093(90)90150-k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026662037"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-3093(90)90150-k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026662037"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00018738800101359", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032287558"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/00018738800101359", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032287558"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9517(88)90164-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032453533"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0021-9517(92)90182-h", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034607598"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0038-1098(89)90555-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040797924"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0038-1098(89)90555-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040797924"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/sia.740160173", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048373649"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/sia.740160173", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048373649"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1111/j.1151-2916.1986.tb07459.x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052903830"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01145a126", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055773283"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la00073a020", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056140457"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1143/jpsj.56.2201", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1063109759"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1992-06", 
    "datePublishedReg": "1992-06-01", 
    "description": "The preparation by a sol-gel process of TiO2-CeO2 supports (Ce/Ti atomic ratio=1/1) was studied by varying the sol-gel processing conditions. Starting materials were Ti[OCH(CH3)2]4 and CeCl3-7H2O. The samples were characterised before and after calcination at 400 \u00b0C by BET, porosity measurements, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Working in acidic conditions leads to the formation of a compound that induces the growth of CeO2 on amorphous TiO2 during calcination. In a basic medium, a well defined CeTiO3 compound is obtained that allows the formation of a real mixed TiO2-CeO2 compound after calcination. It presents a specific area of 70 m2 g\u22121, a narrow distribution of mesopores and easily reducible cerium oxide.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00765231", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1126974", 
        "issn": [
          "1011-372X", 
          "1572-879X"
        ], 
        "name": "Catalysis Letters", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "14"
      }
    ], 
    "name": "Influence of the preparation method on the characteristics of TiO2-CeO2 supports", 
    "pagination": "171-183", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "c612ac2836c8a9d4b4054f7b1b556429da93d64b4bb1b85240f23541eaba8821"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00765231"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1041579967"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00765231", 
      "https://app.dimensions.ai/details/publication/pub.1041579967"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T22:27", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8690_00000490.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007/BF00765231"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00765231'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00765231'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00765231'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00765231'


 

This table displays all metadata directly associated to this object as RDF triples.

127 TRIPLES      21 PREDICATES      44 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00765231 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nf7bcdf07143841c4affdfafbdeafc4d8
4 schema:citation sg:pub.10.1007/bf00765318
5 https://doi.org/10.1002/sia.740160173
6 https://doi.org/10.1002/zaac.19663430309
7 https://doi.org/10.1016/0021-9517(74)90201-2
8 https://doi.org/10.1016/0021-9517(88)90164-9
9 https://doi.org/10.1016/0021-9517(92)90182-h
10 https://doi.org/10.1016/0022-3093(90)90149-g
11 https://doi.org/10.1016/0022-3093(90)90150-k
12 https://doi.org/10.1016/0038-1098(85)90223-6
13 https://doi.org/10.1016/0038-1098(89)90555-3
14 https://doi.org/10.1016/s0166-9834(00)80196-7
15 https://doi.org/10.1016/s0166-9834(00)82873-0
16 https://doi.org/10.1021/ja01145a126
17 https://doi.org/10.1021/la00073a020
18 https://doi.org/10.1080/00018738800101359
19 https://doi.org/10.1111/j.1151-2916.1986.tb07459.x
20 https://doi.org/10.1143/jpsj.56.2201
21 schema:datePublished 1992-06
22 schema:datePublishedReg 1992-06-01
23 schema:description The preparation by a sol-gel process of TiO2-CeO2 supports (Ce/Ti atomic ratio=1/1) was studied by varying the sol-gel processing conditions. Starting materials were Ti[OCH(CH3)2]4 and CeCl3-7H2O. The samples were characterised before and after calcination at 400 °C by BET, porosity measurements, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Working in acidic conditions leads to the formation of a compound that induces the growth of CeO2 on amorphous TiO2 during calcination. In a basic medium, a well defined CeTiO3 compound is obtained that allows the formation of a real mixed TiO2-CeO2 compound after calcination. It presents a specific area of 70 m2 g−1, a narrow distribution of mesopores and easily reducible cerium oxide.
24 schema:genre research_article
25 schema:inLanguage en
26 schema:isAccessibleForFree false
27 schema:isPartOf N0c4e653d6fe842ad9fad5e28fecbb63f
28 Ncc7b326b0c654902bdc266b4201c356f
29 sg:journal.1126974
30 schema:name Influence of the preparation method on the characteristics of TiO2-CeO2 supports
31 schema:pagination 171-183
32 schema:productId N541547822e3d4bbfab6993f6aa75aac4
33 Nb2ddb3e1170a497ba0ff25c4439e1fd5
34 Nc6785428a5fb41e39c64d74c1f32e0fb
35 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041579967
36 https://doi.org/10.1007/bf00765231
37 schema:sdDatePublished 2019-04-10T22:27
38 schema:sdLicense https://scigraph.springernature.com/explorer/license/
39 schema:sdPublisher Na97a5ee253a2492f9645c8b5631ce3dd
40 schema:url http://link.springer.com/10.1007/BF00765231
41 sgo:license sg:explorer/license/
42 sgo:sdDataset articles
43 rdf:type schema:ScholarlyArticle
44 N0c4e653d6fe842ad9fad5e28fecbb63f schema:issueNumber 2
45 rdf:type schema:PublicationIssue
46 N541547822e3d4bbfab6993f6aa75aac4 schema:name readcube_id
47 schema:value c612ac2836c8a9d4b4054f7b1b556429da93d64b4bb1b85240f23541eaba8821
48 rdf:type schema:PropertyValue
49 Na97a5ee253a2492f9645c8b5631ce3dd schema:name Springer Nature - SN SciGraph project
50 rdf:type schema:Organization
51 Nb2ddb3e1170a497ba0ff25c4439e1fd5 schema:name doi
52 schema:value 10.1007/bf00765231
53 rdf:type schema:PropertyValue
54 Nbfedbf61968649c5bace3837917b7cc4 rdf:first sg:person.010654125447.03
55 rdf:rest rdf:nil
56 Nc18eff4eb9104c868c4af50e344cd896 rdf:first sg:person.07516213064.88
57 rdf:rest Nbfedbf61968649c5bace3837917b7cc4
58 Nc6785428a5fb41e39c64d74c1f32e0fb schema:name dimensions_id
59 schema:value pub.1041579967
60 rdf:type schema:PropertyValue
61 Ncc7b326b0c654902bdc266b4201c356f schema:volumeNumber 14
62 rdf:type schema:PublicationVolume
63 Nf7bcdf07143841c4affdfafbdeafc4d8 rdf:first sg:person.0716277067.05
64 rdf:rest Nc18eff4eb9104c868c4af50e344cd896
65 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
66 schema:name Chemical Sciences
67 rdf:type schema:DefinedTerm
68 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
69 schema:name Physical Chemistry (incl. Structural)
70 rdf:type schema:DefinedTerm
71 sg:journal.1126974 schema:issn 1011-372X
72 1572-879X
73 schema:name Catalysis Letters
74 rdf:type schema:Periodical
75 sg:person.010654125447.03 schema:affiliation https://www.grid.ac/institutes/grid.11843.3f
76 schema:familyName Hilaire
77 schema:givenName L.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010654125447.03
79 rdf:type schema:Person
80 sg:person.0716277067.05 schema:affiliation https://www.grid.ac/institutes/grid.11843.3f
81 schema:familyName Dauscher
82 schema:givenName A.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0716277067.05
84 rdf:type schema:Person
85 sg:person.07516213064.88 schema:affiliation https://www.grid.ac/institutes/grid.11843.3f
86 schema:familyName Wehrer
87 schema:givenName P.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07516213064.88
89 rdf:type schema:Person
90 sg:pub.10.1007/bf00765318 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019401871
91 https://doi.org/10.1007/bf00765318
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1002/sia.740160173 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048373649
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1002/zaac.19663430309 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000691382
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/0021-9517(74)90201-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011564182
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1016/0021-9517(88)90164-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032453533
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1016/0021-9517(92)90182-h schema:sameAs https://app.dimensions.ai/details/publication/pub.1034607598
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1016/0022-3093(90)90149-g schema:sameAs https://app.dimensions.ai/details/publication/pub.1021970344
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1016/0022-3093(90)90150-k schema:sameAs https://app.dimensions.ai/details/publication/pub.1026662037
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1016/0038-1098(85)90223-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021004973
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1016/0038-1098(89)90555-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040797924
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1016/s0166-9834(00)80196-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017024823
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1016/s0166-9834(00)82873-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002003683
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1021/ja01145a126 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055773283
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1021/la00073a020 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056140457
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1080/00018738800101359 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032287558
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1111/j.1151-2916.1986.tb07459.x schema:sameAs https://app.dimensions.ai/details/publication/pub.1052903830
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1143/jpsj.56.2201 schema:sameAs https://app.dimensions.ai/details/publication/pub.1063109759
124 rdf:type schema:CreativeWork
125 https://www.grid.ac/institutes/grid.11843.3f schema:alternateName University of Strasbourg
126 schema:name Laboratoire d'Etude de la Réactivité Catalytique, des Surfaces et Interfaces, URA 1498 du CNRS, Université Louis Pasteur, 4 rue Blaise Pascal, 67070, Strasbourg Cedex, France
127 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...