Effect of starting salt on catalytic behaviour of Cu-ZrO2 catalysts in methanol synthesis from carbon dioxide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-03

AUTHORS

Yuriko Nitta, Tomohiro Fujimatsu, Yasuaki Okamoto, Toshinobu Imanaka

ABSTRACT

Starting salts used in the co-precipitation of Cu-ZrO2 precursors had marked influence on both activity and selectivity of resulting catalysts for methanol synthesis: chlorides increased the selectivity, suggesting the structure sensitivity of methanol formation reaction, while sulfates much enhanced the activity by affecting the dispersion of Zr species. A simultaneous use of copper chloride and zirconium sulfate greatly improved the activity and selectivity of the catalyst for methanol formation. More... »

PAGES

157-165

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00763938

DOI

http://dx.doi.org/10.1007/bf00763938

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002970638


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan", 
          "id": "http://www.grid.ac/institutes/grid.136593.b", 
          "name": [
            "Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nitta", 
        "givenName": "Yuriko", 
        "id": "sg:person.012645476525.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012645476525.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan", 
          "id": "http://www.grid.ac/institutes/grid.136593.b", 
          "name": [
            "Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fujimatsu", 
        "givenName": "Tomohiro", 
        "id": "sg:person.011712504547.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011712504547.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan", 
          "id": "http://www.grid.ac/institutes/grid.136593.b", 
          "name": [
            "Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Okamoto", 
        "givenName": "Yasuaki", 
        "id": "sg:person.015601115705.73", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015601115705.73"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan", 
          "id": "http://www.grid.ac/institutes/grid.136593.b", 
          "name": [
            "Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Imanaka", 
        "givenName": "Toshinobu", 
        "id": "sg:person.012401201246.82", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012401201246.82"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/bf00772095", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045638865", 
          "https://doi.org/10.1007/bf00772095"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1993-03", 
    "datePublishedReg": "1993-03-01", 
    "description": "Starting salts used in the co-precipitation of Cu-ZrO2 precursors had marked influence on both activity and selectivity of resulting catalysts for methanol synthesis: chlorides increased the selectivity, suggesting the structure sensitivity of methanol formation reaction, while sulfates much enhanced the activity by affecting the dispersion of Zr species. A simultaneous use of copper chloride and zirconium sulfate greatly improved the activity and selectivity of the catalyst for methanol formation.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/bf00763938", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1126974", 
        "issn": [
          "1011-372X", 
          "1572-879X"
        ], 
        "name": "Catalysis Letters", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1-2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "17"
      }
    ], 
    "keywords": [
      "methanol synthesis", 
      "methanol formation reaction", 
      "catalytic behavior", 
      "Zr species", 
      "Cu\u2013ZrO2", 
      "structure sensitivity", 
      "zirconium sulfate", 
      "methanol formation", 
      "formation reaction", 
      "copper chloride", 
      "selectivity", 
      "catalyst", 
      "carbon dioxide", 
      "synthesis", 
      "salt", 
      "chloride", 
      "sulfate", 
      "reaction", 
      "precursors", 
      "dioxide", 
      "dispersion", 
      "formation", 
      "activity", 
      "simultaneous use", 
      "species", 
      "behavior", 
      "sensitivity", 
      "influence", 
      "effect", 
      "use"
    ], 
    "name": "Effect of starting salt on catalytic behaviour of Cu-ZrO2 catalysts in methanol synthesis from carbon dioxide", 
    "pagination": "157-165", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1002970638"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00763938"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00763938", 
      "https://app.dimensions.ai/details/publication/pub.1002970638"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-10-01T06:29", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221001/entities/gbq_results/article/article_252.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/bf00763938"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00763938'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00763938'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00763938'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00763938'


 

This table displays all metadata directly associated to this object as RDF triples.

112 TRIPLES      21 PREDICATES      56 URIs      47 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00763938 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N5e0467ee126045258a1e788b9fef1a6e
4 schema:citation sg:pub.10.1007/bf00772095
5 schema:datePublished 1993-03
6 schema:datePublishedReg 1993-03-01
7 schema:description Starting salts used in the co-precipitation of Cu-ZrO2 precursors had marked influence on both activity and selectivity of resulting catalysts for methanol synthesis: chlorides increased the selectivity, suggesting the structure sensitivity of methanol formation reaction, while sulfates much enhanced the activity by affecting the dispersion of Zr species. A simultaneous use of copper chloride and zirconium sulfate greatly improved the activity and selectivity of the catalyst for methanol formation.
8 schema:genre article
9 schema:isAccessibleForFree false
10 schema:isPartOf N3022dd1081814743b6c40bfb4f0d0913
11 Ne42fcb5805cf4567be599f0629fef7b3
12 sg:journal.1126974
13 schema:keywords Cu–ZrO2
14 Zr species
15 activity
16 behavior
17 carbon dioxide
18 catalyst
19 catalytic behavior
20 chloride
21 copper chloride
22 dioxide
23 dispersion
24 effect
25 formation
26 formation reaction
27 influence
28 methanol formation
29 methanol formation reaction
30 methanol synthesis
31 precursors
32 reaction
33 salt
34 selectivity
35 sensitivity
36 simultaneous use
37 species
38 structure sensitivity
39 sulfate
40 synthesis
41 use
42 zirconium sulfate
43 schema:name Effect of starting salt on catalytic behaviour of Cu-ZrO2 catalysts in methanol synthesis from carbon dioxide
44 schema:pagination 157-165
45 schema:productId N1b0e644169024d0ca54a0e1a0c648512
46 N1c317fd4639f43fd82fb203251a12a0b
47 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002970638
48 https://doi.org/10.1007/bf00763938
49 schema:sdDatePublished 2022-10-01T06:29
50 schema:sdLicense https://scigraph.springernature.com/explorer/license/
51 schema:sdPublisher N5f7fd6d351424fa3aac20f573c8f27dd
52 schema:url https://doi.org/10.1007/bf00763938
53 sgo:license sg:explorer/license/
54 sgo:sdDataset articles
55 rdf:type schema:ScholarlyArticle
56 N1b0e644169024d0ca54a0e1a0c648512 schema:name dimensions_id
57 schema:value pub.1002970638
58 rdf:type schema:PropertyValue
59 N1bfc3b5fd9354b109a5372756dc74903 rdf:first sg:person.011712504547.05
60 rdf:rest N513166b7796a44adbdff82b8288530f3
61 N1c317fd4639f43fd82fb203251a12a0b schema:name doi
62 schema:value 10.1007/bf00763938
63 rdf:type schema:PropertyValue
64 N3022dd1081814743b6c40bfb4f0d0913 schema:issueNumber 1-2
65 rdf:type schema:PublicationIssue
66 N513166b7796a44adbdff82b8288530f3 rdf:first sg:person.015601115705.73
67 rdf:rest N81bff96337264351b95db98d10402bd6
68 N5e0467ee126045258a1e788b9fef1a6e rdf:first sg:person.012645476525.29
69 rdf:rest N1bfc3b5fd9354b109a5372756dc74903
70 N5f7fd6d351424fa3aac20f573c8f27dd schema:name Springer Nature - SN SciGraph project
71 rdf:type schema:Organization
72 N81bff96337264351b95db98d10402bd6 rdf:first sg:person.012401201246.82
73 rdf:rest rdf:nil
74 Ne42fcb5805cf4567be599f0629fef7b3 schema:volumeNumber 17
75 rdf:type schema:PublicationVolume
76 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
77 schema:name Chemical Sciences
78 rdf:type schema:DefinedTerm
79 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
80 schema:name Physical Chemistry (incl. Structural)
81 rdf:type schema:DefinedTerm
82 sg:journal.1126974 schema:issn 1011-372X
83 1572-879X
84 schema:name Catalysis Letters
85 schema:publisher Springer Nature
86 rdf:type schema:Periodical
87 sg:person.011712504547.05 schema:affiliation grid-institutes:grid.136593.b
88 schema:familyName Fujimatsu
89 schema:givenName Tomohiro
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011712504547.05
91 rdf:type schema:Person
92 sg:person.012401201246.82 schema:affiliation grid-institutes:grid.136593.b
93 schema:familyName Imanaka
94 schema:givenName Toshinobu
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012401201246.82
96 rdf:type schema:Person
97 sg:person.012645476525.29 schema:affiliation grid-institutes:grid.136593.b
98 schema:familyName Nitta
99 schema:givenName Yuriko
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012645476525.29
101 rdf:type schema:Person
102 sg:person.015601115705.73 schema:affiliation grid-institutes:grid.136593.b
103 schema:familyName Okamoto
104 schema:givenName Yasuaki
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015601115705.73
106 rdf:type schema:Person
107 sg:pub.10.1007/bf00772095 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045638865
108 https://doi.org/10.1007/bf00772095
109 rdf:type schema:CreativeWork
110 grid-institutes:grid.136593.b schema:alternateName Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan
111 schema:name Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan
112 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...