Quantum-chemical interpretation of regioselective coordination in the series of 2-aminoazole—metal complexes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1995-12

AUTHORS

V. A. Pichko, D. A. Garnovskii, A. S. Burlov, A. D. Garnovskii

ABSTRACT

Relative thermodynamic stabilities and competitive bonding (regioselective coordination) of Pearson acids MCl2 (hard BeCl2, intermediate ZnCl2, and soft HgCl2) with aminohetero-cycles L (2-aminooxazole, 2-aminothiazole, and 2-aminoimidazole) have been calculated by the quantum-chemical MNDO method. It follows from the results of the calculation that in tetrahedral MCl2·2L complexes the coordination bond is formed by the endocyclic pyridine-type nitrogen atom independent of the type of ligands. More... »

PAGES

2274-2276

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00713592

DOI

http://dx.doi.org/10.1007/bf00713592

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039363787


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