Aminosulfuric acid: An excellent guest for crown ether complexation. Crystal structure of the 1∶1∶1 molecular complex between aminosulfuric acid, water ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1995-12

AUTHORS

Yurii A. Simonov, Marina S. Fonari, Janusz Lipkowski, Edward V. Ganin

ABSTRACT

The twenty-membered macrocycle, 18,19-benzo-1, 16-diaza-4,7,10,13-tetraoxacycloeicosa-17,20-dione, C18H26N2O6 (1), aminosulfuric acid and water form a stoichiometric 1∶1∶1 inclusion compound. The crystal structure of [1·NH3+SO3−]·H2O has been determined by X-ray crystallography. The crystal is monoclinic, space groupP21/c, a=7.967(1),b=13.447(3),c=20.779(4) Å, β=90.20(2) Å;Z=4. The finalR-value is 0.0434 for 4638 unique reflections withI>2σ(I). The structure consists of the 1∶1 molecular complexes between the crown host and aminosulfuric acid revealing hydrogen bonding with the ligand ether and carbonyl oxygen atoms. The complexes are united in the layer-like structure by NH...O host-guest and NH...O=C More... »

PAGES

257-268

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00707778

DOI

http://dx.doi.org/10.1007/bf00707778

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040294711


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