Photochemical properties and structures ofN-amino andN-azomethine derivatives of 2,4,6-triphenylpyridinium perchlorates View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1995-02

AUTHORS

O. S. Filipenko, S. M. Aldoshin, G. V. Shilov, N. I. Makarova, V. A. Kharlanov, M. I. Knyazhanskii

ABSTRACT

The molecular structures of the initial compounds and the products of photocyclization involving amino and azomethine groups in perchlorates ofN-amino (1) andN-azomethine (2) derivatives of 2,4,6-triphenylpyridinium cations were studied. Cations1 and2 have an essentially non-coplanar arrangement of the α-Ph rings, and the product of photocyclization of2, cation3, is characterized by a flattened structure. It was found that the orientation of the lone electron pair of the N atom with respect to one of the planes of the α-Ph rings in molecule1 is more favorable for monocyclization involving the amino group. The structure of molecule2 allows two routes of the photoreaction,viz., O → N proton transfer and monocyclization with an α-Ph ring. However, the structural features of molecule2 are more favorable for photocyclization. More... »

PAGES

287-292

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00702137

DOI

http://dx.doi.org/10.1007/bf00702137

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050598868


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0601", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Biochemistry and Cell Biology", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/06", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Biological Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Filipenko", 
        "givenName": "O. S.", 
        "id": "sg:person.013100520031.61", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013100520031.61"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Aldoshin", 
        "givenName": "S. M.", 
        "id": "sg:person.013232115673.09", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013232115673.09"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shilov", 
        "givenName": "G. V.", 
        "id": "sg:person.011533564071.36", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011533564071.36"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Research Institute of Physical and Organic Chemistry, Rostov State University, 344038, Rostov-on-Don"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Makarova", 
        "givenName": "N. I.", 
        "id": "sg:person.0762174631.57", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0762174631.57"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Research Institute of Physical and Organic Chemistry, Rostov State University, 344038, Rostov-on-Don"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kharlanov", 
        "givenName": "V. A.", 
        "id": "sg:person.010173303517.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010173303517.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University", 
          "id": "https://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Research Institute of Physical and Organic Chemistry, Rostov State University, 344038, Rostov-on-Don"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Knyazhanskii", 
        "givenName": "M. I.", 
        "id": "sg:person.014037513333.51", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014037513333.51"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/1010-6030(90)87012-z", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028093881"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/jr9640002068", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041419213"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0567740878009449", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048290682"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100818a030", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055680221"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3987/r-1987-04-0969", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1071778939"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1995-02", 
    "datePublishedReg": "1995-02-01", 
    "description": "The molecular structures of the initial compounds and the products of photocyclization involving amino and azomethine groups in perchlorates ofN-amino (1) andN-azomethine (2) derivatives of 2,4,6-triphenylpyridinium cations were studied. Cations1 and2 have an essentially non-coplanar arrangement of the \u03b1-Ph rings, and the product of photocyclization of2, cation3, is characterized by a flattened structure. It was found that the orientation of the lone electron pair of the N atom with respect to one of the planes of the \u03b1-Ph rings in molecule1 is more favorable for monocyclization involving the amino group. The structure of molecule2 allows two routes of the photoreaction,viz., O \u2192 N proton transfer and monocyclization with an \u03b1-Ph ring. However, the structural features of molecule2 are more favorable for photocyclization.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/bf00702137", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "44"
      }
    ], 
    "name": "Photochemical properties and structures ofN-amino andN-azomethine derivatives of 2,4,6-triphenylpyridinium perchlorates", 
    "pagination": "287-292", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "f1090a0556093e9741e0b2aaaf8a0f3620f4d0f74e55922e0bd04f438e560242"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/bf00702137"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1050598868"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/bf00702137", 
      "https://app.dimensions.ai/details/publication/pub.1050598868"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T14:20", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000372_0000000372/records_117121_00000002.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2FBF00702137"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00702137'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00702137'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00702137'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00702137'


 

This table displays all metadata directly associated to this object as RDF triples.

114 TRIPLES      21 PREDICATES      32 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/bf00702137 schema:about anzsrc-for:06
2 anzsrc-for:0601
3 schema:author N1d28a9e11c264b219211d2b31f356712
4 schema:citation https://doi.org/10.1016/1010-6030(90)87012-z
5 https://doi.org/10.1021/j100818a030
6 https://doi.org/10.1039/jr9640002068
7 https://doi.org/10.1107/s0567740878009449
8 https://doi.org/10.3987/r-1987-04-0969
9 schema:datePublished 1995-02
10 schema:datePublishedReg 1995-02-01
11 schema:description The molecular structures of the initial compounds and the products of photocyclization involving amino and azomethine groups in perchlorates ofN-amino (1) andN-azomethine (2) derivatives of 2,4,6-triphenylpyridinium cations were studied. Cations1 and2 have an essentially non-coplanar arrangement of the α-Ph rings, and the product of photocyclization of2, cation3, is characterized by a flattened structure. It was found that the orientation of the lone electron pair of the N atom with respect to one of the planes of the α-Ph rings in molecule1 is more favorable for monocyclization involving the amino group. The structure of molecule2 allows two routes of the photoreaction,viz., O → N proton transfer and monocyclization with an α-Ph ring. However, the structural features of molecule2 are more favorable for photocyclization.
12 schema:genre research_article
13 schema:inLanguage en
14 schema:isAccessibleForFree false
15 schema:isPartOf N1a24848c8ef44afaac00c5689c17c35e
16 N4c207c47d03d40bdaa790e25de47bbe2
17 sg:journal.1022309
18 schema:name Photochemical properties and structures ofN-amino andN-azomethine derivatives of 2,4,6-triphenylpyridinium perchlorates
19 schema:pagination 287-292
20 schema:productId N826b3723613147c4a62a0922b71cdefa
21 N834f9dd17da5437787a145fdc2af9ace
22 Nb4d6af4b020e47d1812c014999a87260
23 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050598868
24 https://doi.org/10.1007/bf00702137
25 schema:sdDatePublished 2019-04-11T14:20
26 schema:sdLicense https://scigraph.springernature.com/explorer/license/
27 schema:sdPublisher N5119eacc05a540e4be000b1ab277bce1
28 schema:url http://link.springer.com/10.1007%2FBF00702137
29 sgo:license sg:explorer/license/
30 sgo:sdDataset articles
31 rdf:type schema:ScholarlyArticle
32 N0ffa2e08d5af4da8a7f134c95cef645a rdf:first sg:person.013232115673.09
33 rdf:rest N761b5a563a9649faae90d9000c456fce
34 N1a24848c8ef44afaac00c5689c17c35e schema:volumeNumber 44
35 rdf:type schema:PublicationVolume
36 N1d28a9e11c264b219211d2b31f356712 rdf:first sg:person.013100520031.61
37 rdf:rest N0ffa2e08d5af4da8a7f134c95cef645a
38 N4c207c47d03d40bdaa790e25de47bbe2 schema:issueNumber 2
39 rdf:type schema:PublicationIssue
40 N5119eacc05a540e4be000b1ab277bce1 schema:name Springer Nature - SN SciGraph project
41 rdf:type schema:Organization
42 N5e17f890ae5f48d3a98f9e02f76aa9f3 rdf:first sg:person.0762174631.57
43 rdf:rest N8d2ee66497c049ee8c529bb3b2982779
44 N761b5a563a9649faae90d9000c456fce rdf:first sg:person.011533564071.36
45 rdf:rest N5e17f890ae5f48d3a98f9e02f76aa9f3
46 N826b3723613147c4a62a0922b71cdefa schema:name dimensions_id
47 schema:value pub.1050598868
48 rdf:type schema:PropertyValue
49 N834f9dd17da5437787a145fdc2af9ace schema:name doi
50 schema:value 10.1007/bf00702137
51 rdf:type schema:PropertyValue
52 N8d2ee66497c049ee8c529bb3b2982779 rdf:first sg:person.010173303517.52
53 rdf:rest Nf828e49181b54fd0b4564de75f0fd7b3
54 Nb4d6af4b020e47d1812c014999a87260 schema:name readcube_id
55 schema:value f1090a0556093e9741e0b2aaaf8a0f3620f4d0f74e55922e0bd04f438e560242
56 rdf:type schema:PropertyValue
57 Nf828e49181b54fd0b4564de75f0fd7b3 rdf:first sg:person.014037513333.51
58 rdf:rest rdf:nil
59 anzsrc-for:06 schema:inDefinedTermSet anzsrc-for:
60 schema:name Biological Sciences
61 rdf:type schema:DefinedTerm
62 anzsrc-for:0601 schema:inDefinedTermSet anzsrc-for:
63 schema:name Biochemistry and Cell Biology
64 rdf:type schema:DefinedTerm
65 sg:journal.1022309 schema:issn 1066-5285
66 1573-9171
67 schema:name Russian Chemical Bulletin
68 rdf:type schema:Periodical
69 sg:person.010173303517.52 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
70 schema:familyName Kharlanov
71 schema:givenName V. A.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010173303517.52
73 rdf:type schema:Person
74 sg:person.011533564071.36 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
75 schema:familyName Shilov
76 schema:givenName G. V.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011533564071.36
78 rdf:type schema:Person
79 sg:person.013100520031.61 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
80 schema:familyName Filipenko
81 schema:givenName O. S.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013100520031.61
83 rdf:type schema:Person
84 sg:person.013232115673.09 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
85 schema:familyName Aldoshin
86 schema:givenName S. M.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013232115673.09
88 rdf:type schema:Person
89 sg:person.014037513333.51 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
90 schema:familyName Knyazhanskii
91 schema:givenName M. I.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014037513333.51
93 rdf:type schema:Person
94 sg:person.0762174631.57 schema:affiliation https://www.grid.ac/institutes/grid.182798.d
95 schema:familyName Makarova
96 schema:givenName N. I.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0762174631.57
98 rdf:type schema:Person
99 https://doi.org/10.1016/1010-6030(90)87012-z schema:sameAs https://app.dimensions.ai/details/publication/pub.1028093881
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1021/j100818a030 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055680221
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1039/jr9640002068 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041419213
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1107/s0567740878009449 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048290682
106 rdf:type schema:CreativeWork
107 https://doi.org/10.3987/r-1987-04-0969 schema:sameAs https://app.dimensions.ai/details/publication/pub.1071778939
108 rdf:type schema:CreativeWork
109 https://www.grid.ac/institutes/grid.182798.d schema:alternateName Southern Federal University
110 schema:name Research Institute of Physical and Organic Chemistry, Rostov State University, 344038, Rostov-on-Don
111 rdf:type schema:Organization
112 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
113 schema:name Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation
114 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...