Preparation and reactivity of metal-containing monomers View Full Text


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Article Info

DATE

1993-01

AUTHORS

A. G. Starikov, G. I. Dzhardimalieva, I. E. Uflyand, T. K. Goncharov, A. D. Pomogailo

ABSTRACT

Metal-containing monomers based on vinyl derivatives of heterocycles (4-vinylpyridine, 3,5-dimethyl-1-vinylpyrazole, 2-methyl-5-vinyltetrazole) and NiCl2, CoCl2, CrCl3 have been prepared and characterized by chemical analysis, IR and electron spectroscopy. By means of spectral methods, the complex formation has been shown to involve N atom of the heterocycle, while the exocyclic C = C bond does not participate in the process. The structure of polyhedrons formed has been characterized both in the solid state and in methanol or DMF. The comparison of splitting parameters for different symmetries indicates that in passing from five-membered to six-membered vinylheterocycles, the strength of the ligand field is greatly enhanced. More... »

PAGES

66-70

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00699976

DOI

http://dx.doi.org/10.1007/bf00699976

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040290508


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