Nature of low-lying electron excited states of (η5-cyclopentadienyl) (η7-cycloheptatrienyl)niobium View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1994-04

AUTHORS

S. Yu. Ketkov

ABSTRACT

Electron absorption spectra of (η5-cyclopentadienyl)(η7-cycloheptatrienyl)niobium in solution and in the vapor phase have been measured for the first time. Possible variants of the band assignment for the spectrum of the complex in a solution have been considered. In the spectrum of the vaporous compound the bands at 29570, 31730, and 34630 cm−1 correspond to the electron transitions from the 4d(σ+) orbital to the lowest Rydberg p- and d-levels. The values of Rydberg transition terms and symmetry of p-states have been determined. More... »

PAGES

583-587

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00699828

DOI

http://dx.doi.org/10.1007/bf00699828

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052361612


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