Ontology type: schema:ScholarlyArticle
1993-11
AUTHORSM. G. Voronkov, N. F. Chernov, O. M. Trofimova, T. N. Aksamentova
ABSTRACTThe interactions of sodium salts of 2-mercaptobenzoxazole, 2-mercaptobenzothiazole and 2-mercaptobenzimidazole with (chloromethyl)trimethyl-, chloromethyl(dimethoxy)methylor (chloromethyl)trimethoxysilanes have been shown to result in the corresponding previously unknown (2-heterylthiomethyl)triorganylsilanes. Transetherification of (2-heteryl-thiomethyl)trimethoxysilanes with triethanolamine gives 1-(2-benzoxazolylthiomethyl)-, 1-(2-benzothiazolylthiomethyl)- and 1-(2-benzimidazolylthiomethyl)silatranes. The reaction of the corresponding alkoxysilanes with boron trifluoride etherate leads to (2-benzoxazolylthiomethyl)- and (2-benzothiazolylthiomethyl)-substituted trifluorosilanes and methyldifluorosilanes having a dragonoid chelate structure. By the hydrolysis of (2-heterylthiomethyl)trimethoxysilanes, new organosilicon sorbents, poly(2-heteryl-thiomethyl)silsesquioxanes have been synthesized. More... »
PAGES1883-1886
http://scigraph.springernature.com/pub.10.1007/bf00699009
DOIhttp://dx.doi.org/10.1007/bf00699009
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1032506207
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Voronkov",
"givenName": "M. G.",
"id": "sg:person.016410733065.70",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016410733065.70"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Chernov",
"givenName": "N. F.",
"id": "sg:person.012621274514.60",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012621274514.60"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Trofimova",
"givenName": "O. M.",
"id": "sg:person.010446355057.52",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010446355057.52"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 ul. Favorskogo, 664033, Irkutsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Aksamentova",
"givenName": "T. N.",
"id": "sg:person.014174654161.29",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014174654161.29"
],
"type": "Person"
}
],
"datePublished": "1993-11",
"datePublishedReg": "1993-11-01",
"description": "The interactions of sodium salts of 2-mercaptobenzoxazole, 2-mercaptobenzothiazole and 2-mercaptobenzimidazole with (chloromethyl)trimethyl-, chloromethyl(dimethoxy)methylor (chloromethyl)trimethoxysilanes have been shown to result in the corresponding previously unknown (2-heterylthiomethyl)triorganylsilanes. Transetherification of (2-heteryl-thiomethyl)trimethoxysilanes with triethanolamine gives 1-(2-benzoxazolylthiomethyl)-, 1-(2-benzothiazolylthiomethyl)- and 1-(2-benzimidazolylthiomethyl)silatranes. The reaction of the corresponding alkoxysilanes with boron trifluoride etherate leads to (2-benzoxazolylthiomethyl)- and (2-benzothiazolylthiomethyl)-substituted trifluorosilanes and methyldifluorosilanes having a dragonoid chelate structure. By the hydrolysis of (2-heterylthiomethyl)trimethoxysilanes, new organosilicon sorbents, poly(2-heteryl-thiomethyl)silsesquioxanes have been synthesized.",
"genre": "article",
"id": "sg:pub.10.1007/bf00699009",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1022309",
"issn": [
"1026-3500",
"1066-5285"
],
"name": "Russian Chemical Bulletin",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "11",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "42"
}
],
"keywords": [
"sodium salt",
"benzimidazole",
"reaction",
"heteryl",
"derivatives",
"interaction",
"hydrolysis",
"benzothiazole",
"salt",
"benzoxazole",
"structure",
"boron trifluoride etherate",
"trifluoride etherate",
"organosilicon derivatives",
"triethanolamine",
"chelate structure",
"etherate",
"sorbent",
"transetherification",
"alkoxysilanes",
"trifluorosilane"
],
"name": "Organosilicon derivatives of 2-mercapto-substituted benzoxazoles, benzothiazoles and benzimidazoles",
"pagination": "1883-1886",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1032506207"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/bf00699009"
]
}
],
"sameAs": [
"https://doi.org/10.1007/bf00699009",
"https://app.dimensions.ai/details/publication/pub.1032506207"
],
"sdDataset": "articles",
"sdDatePublished": "2022-05-20T07:19",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_259.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/bf00699009"
}
]
Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/bf00699009'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/bf00699009'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/bf00699009'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/bf00699009'
This table displays all metadata directly associated to this object as RDF triples.
96 TRIPLES
21 PREDICATES
46 URIs
39 LITERALS
6 BLANK NODES