Organosilicon derivatives of 2-mercapto-substituted benzoxazoles, benzothiazoles and benzimidazoles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1993-11

AUTHORS

M. G. Voronkov, N. F. Chernov, O. M. Trofimova, T. N. Aksamentova

ABSTRACT

The interactions of sodium salts of 2-mercaptobenzoxazole, 2-mercaptobenzothiazole and 2-mercaptobenzimidazole with (chloromethyl)trimethyl-, chloromethyl(dimethoxy)methylor (chloromethyl)trimethoxysilanes have been shown to result in the corresponding previously unknown (2-heterylthiomethyl)triorganylsilanes. Transetherification of (2-heteryl-thiomethyl)trimethoxysilanes with triethanolamine gives 1-(2-benzoxazolylthiomethyl)-, 1-(2-benzothiazolylthiomethyl)- and 1-(2-benzimidazolylthiomethyl)silatranes. The reaction of the corresponding alkoxysilanes with boron trifluoride etherate leads to (2-benzoxazolylthiomethyl)- and (2-benzothiazolylthiomethyl)-substituted trifluorosilanes and methyldifluorosilanes having a dragonoid chelate structure. By the hydrolysis of (2-heterylthiomethyl)trimethoxysilanes, new organosilicon sorbents, poly(2-heteryl-thiomethyl)silsesquioxanes have been synthesized. More... »

PAGES

1883-1886

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/bf00699009

DOI

http://dx.doi.org/10.1007/bf00699009

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032506207


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